Lecture

Thermodynamics Principles: Enthalpy and Reactions

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In course

CH-160(b): General chemistry

Cet enseignement vise l'acquisition des notions essentielles relatives à la structure de la matière, aux équilibres et à la réactivité chimiques. Le cours et les exercices fournissent la méthodologie permettant de résoudre par le raisonnement et le calcul ...

Description

This lecture covers the second and third principles of thermodynamics, the standard enthalpy of reaction, internal energy, and the energy of Gibbs. It explains the molecular interpretation of classical thermodynamics, state functions, and the first principle of thermodynamics. The lecture also delves into the concepts of system limits, equilibrium properties, and the study of chemical reactions. Various types of systems, energy conservation, and the calculation of enthalpy changes in reactions are discussed. Additionally, it explores exothermic and endothermic processes, enthalpy of state changes, and the application of Hess's law in determining reaction enthalpies.

Instructor

Samuel Terrettaz

Teaching & PhD Courses Advanced general chemistry CH-160(f) This course aims at the acquisition of essential notions on the structure of matter, chemical equilibria and reactivity. Theoretical teaching and exercise provide the methodology to analyze and solve by reasoning and calculation novel problems of general chemistry. Advanced general chemistry CH-160(g) This course aims at the acquisition of essential notions on the structure of matter, chemical equilibria and reactivi

Official source

Ontological neighbourhood

Physics

Thermodynamics: Statistical mechanics

Related concepts (32)

Enthalpy

Enthalpy ˈɛnθəlpi, a property of a thermodynamic system, is the sum of the system's internal energy and the product of its pressure and volume. It is a state function used in many measurements in chemical, biological, and physical systems at a constant pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work required to establish the system's physical dimensions, i.e. to make room for it by displacing its surroundings.

Non-equilibrium thermodynamics

Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities (non-equilibrium state variables) that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium. Non-equilibrium thermodynamics is concerned with transport processes and with the rates of chemical reactions.

Exothermic process

In thermodynamics, an exothermic process () is a thermodynamic process or reaction that releases energy from the system to its surroundings, usually in the form of heat, but also in a form of light (e.g. a spark, flame, or flash), electricity (e.g. a battery), or sound (e.g. explosion heard when burning hydrogen). The term exothermic was first coined by 19th-century French chemist Marcellin Berthelot. The opposite of an exothermic process is an endothermic process, one that absorbs energy usually in the form of heat.

Endothermic process

In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy H (or internal energy U) of the system. In such a process, a closed system usually absorbs thermal energy from its surroundings, which is heat transfer into the system. Thus, an endothermic reaction generally leads to an increase in the temperature of the system and a decrease in that of the surroundings. It may be a chemical process, such as dissolving ammonium nitrate () in water (), or a physical process, such as the melting of ice cubes.

Thermodynamic state

In thermodynamics, a thermodynamic state of a system is its condition at a specific time; that is, fully identified by values of a suitable set of parameters known as state variables, state parameters or thermodynamic variables. Once such a set of values of thermodynamic variables has been specified for a system, the values of all thermodynamic properties of the system are uniquely determined. Usually, by default, a thermodynamic state is taken to be one of thermodynamic equilibrium.

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