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Lecture

Ceramic Materials: Structures and Properties

In course

MSE-234: Mechanical behaviour of materials

Ce cours est une introduction au comportement mécanique, à l'élaboration, à la structure et au cycle de vie des grandes classes de matériaux de structure (métaux, polymères, céramiques et composites) ...

Description

This lecture covers the nature of atomic bonds in ceramics, their crystal structures, and polymorphic forms. It explains the coordination numbers, geometries, and characteristics of common ceramic structures, emphasizing the relationship between atomic size and crystal packing.

Instructors (3)

Julie Nathalie S Gheysen

Andreas Mortensen

Andreas Mortensen is currently Professor and Director of the Institute of Materials at the Swiss Federal Institute of Technology in Lausanne (EPFL), where he heads the Laboratory for Mechanical Metallurgy. He joined the faculty of EPFL 1997 after ten years, from 1986 to 1996, as a member of the faculty of the Department of Materials Science and Engineering at the Massachusetts Institute of Technology, where he held the successive titles of ALCOA Assistant Professor, Associate Professor, and Professor. His research is focussed on the processing, microstructural development and mechanical behavior of advanced metallic materials with particular focus on metal matrix composites and metal foams, on infiltration processing and capillarity, and on damage and fracture in metallic materials. He is author or co-author of two monographs, around one hundred and eighty scientific or technical publications and twelve patents. Born in San Francisco in 1957, of dual (Danish and US) nationality, Andreas Mortensen graduated in 1980 from the Ecole Nationale Supérieure des Mines de Paris with a Diplôme dIngénieur Civil, and earned his Ph.D. in the Department of Materials Science and Engineering at MIT in 1986. Besides his academic employment, he was a postdoctoral researcher at Nippon Steel during part of 1986, and was invited professor at the Ecole des Mines in Paris during the academic year 1995 to 1996. He is a member of the editorial committee of International Materials Reviews and has co-edited four books. He is a Fellow of ASM, a recipient of the Howe Medal and the Grossman Award of the American Society of Metals, was awarded the Péchiney Prize by the French Academy of Sciences and the Res Metallica Chair from the Katholieke Universiteit Leuven, received three EPFL teaching awards, is one of ISIs Highly Cited authors for Materials Science since 2002 and was awarded an ERC advanced grant in 2012.

David Hernandez Escobar

Official source

Related concepts (32)

Chemical bond

A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules, crystals, and other structures. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of electrons as in covalent bonds. The strength of chemical bonds varies considerably; there are "strong bonds" or "primary bonds" such as covalent, ionic and metallic bonds, and "weak bonds" or "secondary bonds" such as dipole–dipole interactions, the London dispersion force, and hydrogen bonding.

Pi bond

In chemistry, pi bonds (π bonds) are covalent chemical bonds, in each of which two lobes of an orbital on one atom overlap with two lobes of an orbital on another atom, and in which this overlap occurs laterally. Each of these atomic orbitals has an electron density of zero at a shared nodal plane that passes through the two bonded nuclei. This plane also is a nodal plane for the molecular orbital of the pi bond. Pi bonds can form in double and triple bonds but do not form in single bonds in most cases.

Crystal structure

In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in the material that constitutes this repeating pattern is the unit cell of the structure.

Crystal

A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography.

Sigma bond

In chemistry, sigma bonds (σ bonds) are the strongest type of covalent chemical bond. They are formed by head-on overlapping between atomic orbitals. Sigma bonding is most simply defined for diatomic molecules using the language and tools of symmetry groups. In this formal approach, a σ-bond is symmetrical with respect to rotation about the bond axis. By this definition, common forms of sigma bonds are s+s, pz+pz, s+pz and dz2+dz2 (where z is defined as the axis of the bond or the internuclear axis).

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