Lecture

Gibbs Entropy: Definition and Partition Function

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In course

PHYS-105: Advanced physics II (thermodynamics)

Ce cours présente la thermodynamique en tant que théorie permettant une description d'un grand nombre de phénomènes importants en physique, chimie et ingéniere, et d'effets de transport. Une introduction à la physique statistique renforce les notions acqu ...

Description

This lecture covers the definition of Gibbs entropy and its relation to the partition function in statistical mechanics. The instructor explains the concepts of entropy, free energy, and their mathematical expressions, emphasizing the importance of these quantities in understanding the behavior of physical systems.

Instructors (2)

Cécile Hébert

Cécile Hébert was born in France in 1970. She obtained her Ingeneer degree (physics) and her PhD degree (design of a new energy filter for transmission electron microscopy, under the direction of Prof. B. Jouffrey) at the Ecole Centrale in Paris. As a post doc with Prof. P. Schattschneider, she was working on the calculation of the fine structure of ionisation edges in EELS. As a research assistant at the Vienna University of Technology, she was one of the main participant to the CHIRALTEM project dealing with the measurement of magnetic circular dichroism in the electron microscope.

Jean-Philippe Ansermet

Jean-Philippe Ansermet was born March 1, 1957 in Lausanne (legal origin Vaumarcus, NE). He obtained a diploma as physics engineer of EPFL in 1980. He went on to get a PhD from the University of Illinois at Urbana-Champaign where, from 1985 to 1987, he persued as post-doc with Prof. Slichter his research on catalysis by solid state NMR studies of molecules bound to the surface of catalysts. From 1987 to 1992 he worked at the materials research center of Ciba-Geigy, on polymers for microelectronics, composites, dielectrics and organic charge transfer complexes. In March 1992, as professor of experimental physics, he developed a laboratory on the theme of nanostructured materials and turned full professor in 1995. Since 1992, he teaches classical mechanics, first to future engineering students, since 2004 to physics majors. Since 2000, he teaches thermodynamics also, to the same group of students. He offers a graduate course in spintronics, and another on spin dynamics. His research activities concern the fabrication and properties of magnetic nanostructures produced by electrodeposition. His involvement since the early days of spintronics have allowed him to gain recognition for his work on giant magnetoresistance (CPP-GMR), magnetic relaxation of single nanostructures, and was among the leading groups demonstrating magnetization reversal by spin-polarized currents. Furthermore, his group uses nuclear magnetic resonance , on the one hand as means of investigation of surfaces and electrodes, on the other hand, as a local probe of the electronic properties of complex ferromagnetic oxides.

Official source

Ontological neighbourhood

Physics

Thermodynamics: Statistical mechanics

Related concepts (23)

Partition function (statistical mechanics)

In physics, a partition function describes the statistical properties of a system in thermodynamic equilibrium. Partition functions are functions of the thermodynamic state variables, such as the temperature and volume. Most of the aggregate thermodynamic variables of the system, such as the total energy, free energy, entropy, and pressure, can be expressed in terms of the partition function or its derivatives. The partition function is dimensionless.

Statistical mechanics

In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Sometimes called statistical physics or statistical thermodynamics, its applications include many problems in the fields of physics, biology, chemistry, and neuroscience.

Quantum statistical mechanics

Quantum statistical mechanics is statistical mechanics applied to quantum mechanical systems. In quantum mechanics a statistical ensemble (probability distribution over possible quantum states) is described by a density operator S, which is a non-negative, self-adjoint, trace-class operator of trace 1 on the Hilbert space H describing the quantum system. This can be shown under various mathematical formalisms for quantum mechanics. One such formalism is provided by quantum logic.

Ensemble (mathematical physics)

In physics, specifically statistical mechanics, an ensemble (also statistical ensemble) is an idealization consisting of a large number of virtual copies (sometimes infinitely many) of a system, considered all at once, each of which represents a possible state that the real system might be in. In other words, a statistical ensemble is a set of systems of particles used in statistical mechanics to describe a single system. The concept of an ensemble was introduced by J. Willard Gibbs in 1902.

Helmholtz free energy

In thermodynamics, the Helmholtz free energy (or Helmholtz energy) is a thermodynamic potential that measures the useful work obtainable from a closed thermodynamic system at a constant temperature (isothermal). The change in the Helmholtz energy during a process is equal to the maximum amount of work that the system can perform in a thermodynamic process in which temperature is held constant. At constant temperature, the Helmholtz free energy is minimized at equilibrium.

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