Lecture

Curvature of State Functions

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In course

PHYS-105: Advanced physics II (thermodynamics)

Ce cours présente la thermodynamique en tant que théorie permettant une description d'un grand nombre de phénomènes importants en physique, chimie et ingéniere, et d'effets de transport. Une introduction à la physique statistique renforce les notions acqu ...

Description

This lecture covers the concavity of entropy in isolated systems with two subsystems separated by a wall, discussing the stability and coexistence when the wall is removed. It also explores the curvature of potentials and their relation to the thermodynamic properties.

Instructors (2)

Jean-Philippe Ansermet

Jean-Philippe Ansermet was born March 1, 1957 in Lausanne (legal origin Vaumarcus, NE). He obtained a diploma as physics engineer of EPFL in 1980. He went on to get a PhD from the University of Illinois at Urbana-Champaign where, from 1985 to 1987, he persued as post-doc with Prof. Slichter his research on catalysis by solid state NMR studies of molecules bound to the surface of catalysts. From 1987 to 1992 he worked at the materials research center of Ciba-Geigy, on polymers for microelectronics, composites, dielectrics and organic charge transfer complexes. In March 1992, as professor of experimental physics, he developed a laboratory on the theme of nanostructured materials and turned full professor in 1995. Since 1992, he teaches classical mechanics, first to future engineering students, since 2004 to physics majors. Since 2000, he teaches thermodynamics also, to the same group of students. He offers a graduate course in spintronics, and another on spin dynamics. His research activities concern the fabrication and properties of magnetic nanostructures produced by electrodeposition. His involvement since the early days of spintronics have allowed him to gain recognition for his work on giant magnetoresistance (CPP-GMR), magnetic relaxation of single nanostructures, and was among the leading groups demonstrating magnetization reversal by spin-polarized currents. Furthermore, his group uses nuclear magnetic resonance , on the one hand as means of investigation of surfaces and electrodes, on the other hand, as a local probe of the electronic properties of complex ferromagnetic oxides.

Cécile Hébert

Cécile Hébert was born in France in 1970. She obtained her Ingeneer degree (physics) and her PhD degree (design of a new energy filter for transmission electron microscopy, under the direction of Prof. B. Jouffrey) at the Ecole Centrale in Paris. As a post doc with Prof. P. Schattschneider, she was working on the calculation of the fine structure of ionisation edges in EELS. As a research assistant at the Vienna University of Technology, she was one of the main participant to the CHIRALTEM project dealing with the measurement of magnetic circular dichroism in the electron microscope.

Official source

Ontological neighbourhood

Physics

Thermodynamics: Statistical mechanics

Mathematics

Geometry: Differential geometry

Related concepts (32)

Thermodynamic potential

A thermodynamic potential (or more accurately, a thermodynamic potential energy) is a scalar quantity used to represent the thermodynamic state of a system. Just as in mechanics, where potential energy is defined as capacity to do work, similarly different potentials have different meanings. The concept of thermodynamic potentials was introduced by Pierre Duhem in 1886. Josiah Willard Gibbs in his papers used the term fundamental functions. One main thermodynamic potential that has a physical interpretation is the internal energy U.

Thermodynamic equations

Thermodynamics is expressed by a mathematical framework of thermodynamic equations which relate various thermodynamic quantities and physical properties measured in a laboratory or production process. Thermodynamics is based on a fundamental set of postulates, that became the laws of thermodynamics. One of the fundamental thermodynamic equations is the description of thermodynamic work in analogy to mechanical work, or weight lifted through an elevation against gravity, as defined in 1824 by French physicist Sadi Carnot.

Intensive and extensive properties

Physical properties of materials and systems can often be categorized as being either intensive or extensive, according to how the property changes when the size (or extent) of the system changes. According to IUPAC, an intensive quantity is one whose magnitude is independent of the size of the system, whereas an extensive quantity is one whose magnitude is additive for subsystems. The terms "intensive and extensive quantities" were introduced into physics by German writer Georg Helm in 1898, and by American physicist and chemist Richard C.

Thermodynamic equilibrium

Thermodynamic equilibrium is an axiomatic concept of thermodynamics. It is an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable walls. In thermodynamic equilibrium, there are no net macroscopic flows of matter nor of energy within a system or between systems. In a system that is in its own state of internal thermodynamic equilibrium, no macroscopic change occurs.

Conjugate variables (thermodynamics)

In thermodynamics, the internal energy of a system is expressed in terms of pairs of conjugate variables such as temperature and entropy, pressure and volume, or chemical potential and particle number. In fact, all thermodynamic potentials are expressed in terms of conjugate pairs. The product of two quantities that are conjugate has units of energy or sometimes power. For a mechanical system, a small increment of energy is the product of a force times a small displacement. A similar situation exists in thermodynamics.

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