Lecture

Thermodynamic Potentials: Lagrangian Mechanics and Energy Relations

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In course

PHYS-106(d): General physics : thermodynamics

Le but du cours de Physique générale est de donner à l'étudiant les notions de base nécessaires à la compréhension des phénomènes physiques. L'objectif est atteint lorsque l'étudiant est capable de prévoir quantitativement les conséquences de ces phénomène ...

Description

This lecture covers the transformation from Hamiltonian to Lagrangian mechanics, focusing on thermodynamic potentials. The instructor explains the Lagrangian as the negative of the Legendre transformation of energy, detailing the relationship between kinetic and potential energy in mechanical systems. The discussion includes systems of identical material points, their state variables, and the equations of motion derived from Lagrangian mechanics. The instructor emphasizes the importance of understanding energy as a state function, which is influenced by position and momentum. The lecture also introduces the equations of Lagrange in thermodynamics, addressing the first and second principles, and the role of entropy in irreversible processes. The instructor models a system of points in a viscous fluid, illustrating how energy transformations relate to thermodynamic principles. The lecture concludes with a practical demonstration involving a chain of coupled harmonic oscillators, reinforcing the theoretical concepts presented throughout the session.

Instructor

Sylvain Bréchet

Sylvain Bréchet was born on October 13th, 1981 in Moudon (legal origin Epesses, VD, Switzerland). He obtained a Master of Science in physics at EPFL in 2005. He went on to Cambridge for his PhD studies in theoretical cosmology from 2005 to 2009 under the supervision of Prof. Lasenby (FRS) and Prof. Michael Hobson at the Cavendish Laboratory of the University of Cambridge. He went back to EPFL where he is since 2010 university lecturer and research scientist in the Institute of Condensed Matter Physics. He taught classical mechanics, special relativity and thermodynamics to mechanical, electrical engineering students and physics students. He is currently writing a textbook in thermodynamics.

Official source

Ontological neighbourhood

Physics

Thermodynamics: Statistical mechanics

Mechanics: Classical mechanics

Related concepts (32)

Thermodynamics

Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics.

Laws of thermodynamics

The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships between them. They state empirical facts that form a basis of precluding the possibility of certain phenomena, such as perpetual motion.

Thermodynamic equilibrium

Thermodynamic equilibrium is an axiomatic concept of thermodynamics. It is an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable walls. In thermodynamic equilibrium, there are no net macroscopic flows of matter nor of energy within a system or between systems. In a system that is in its own state of internal thermodynamic equilibrium, no macroscopic change occurs.

Chemical thermodynamics

Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the study of chemical questions and the spontaneity of processes. The structure of chemical thermodynamics is based on the first two laws of thermodynamics.

Non-equilibrium thermodynamics

Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities (non-equilibrium state variables) that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium. Non-equilibrium thermodynamics is concerned with transport processes and with the rates of chemical reactions.

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