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This lecture covers the identification of degradation pathways in (bio)molecular photoelectrochemical systems, focusing on artificial photosynthesis and various types of photoelectrodes. It discusses modifications of electrode supports, desorption of dye-catalyst assemblies, and the protection of binding sites. The speaker presents collaborations with different research institutions and emphasizes the importance of understanding catalyst and linker degradation mechanisms for the development of stable photoelectrochemical devices.