Lecture

Thermodynamics: Fundamental Relations

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Description

This lecture covers the fundamental relations in thermodynamics, including the Gibbs relation, internal energy, entropy, volume, and number of moles. It also explores the Euler relation, extensivity of internal energy, temperature, pressure, and chemical potential. The Gibbs-Duhem relation and the state space equation are discussed, emphasizing the space of states and the equation of state.

In MOOC

Thermodynamics II

The aim of the course is to enable students to understand and apply the fundamental concepts of thermodynamics. After presenting the first and second principles of thermodynamics, the lecture will address questions of irreversibility and thermodynamic potentials. After establishing these conceptual foundations, which are the subject of the first part, their engineering applications, such as heat transfer, calorimetry and phase transitions, will be covered. Next, we'll look at the conversion of chemical en

Official source

Ontological neighbourhood

Physics

Thermodynamics: Statistical mechanics

Related concepts (30)

Chemical thermodynamics

Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the study of chemical questions and the spontaneity of processes. The structure of chemical thermodynamics is based on the first two laws of thermodynamics.

Thermodynamics

Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics.

Laws of thermodynamics

The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships between them. They state empirical facts that form a basis of precluding the possibility of certain phenomena, such as perpetual motion.

Chemical potential

In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a species in a mixture is defined as the rate of change of free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system.

Temperature

Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied on various reference points and thermometric substances for definition. The most common scales are the Celsius scale with the unit symbol °C (formerly called centigrade), the Fahrenheit scale (°F), and the Kelvin scale (K), the latter being used predominantly for scientific purposes.

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