Reaction rate constantIn chemical kinetics, a reaction rate constant or reaction rate coefficient (k) is a proportionality constant which quantifies the rate and direction of a chemical reaction by relating it with the concentration of reactants. For a reaction between reactants A and B to form a product C, where A and B are reactants C is a product a, b, and c are stoichiometric coefficients, the reaction rate is often found to have the form: Here k is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the solution.
Rate equationIn chemistry, the rate law or rate equation for a chemical reaction is a mathematical equation that links the rate of forward reaction with the concentrations or pressures of the reactants and constant parameters (normally rate coefficients and partial reaction orders). For many reactions, the initial rate is given by a power law such as where [\mathrm{A}] and [\mathrm{B}] express the concentration of the species \mathrm{A} and \mathrm{B}, usually in moles per liter (molarity, M).
Reaction rateThe reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. Reaction rates can vary dramatically. For example, the oxidative rusting of iron under Earth's atmosphere is a slow reaction that can take many years, but the combustion of cellulose in a fire is a reaction that takes place in fractions of a second.
Environmental scienceEnvironmental science is an interdisciplinary academic field that integrates physics, biology, and geography (including ecology, chemistry, plant science, zoology, mineralogy, oceanography, limnology, soil science, geology and physical geography, and atmospheric science) to the study of the environment, and the solution of environmental problems. Environmental science emerged from the fields of natural history and medicine during the Enlightenment. Today it provides an integrated, quantitative, and interdisciplinary approach to the study of environmental systems.
Natural environmentThe natural environment or natural world encompasses all living and non-living things occurring naturally, meaning in this case not artificial. The term is most often applied to Earth or some parts of Earth. This environment encompasses the interaction of all living species, climate, weather and natural resources that affect human survival and economic activity.
Environmental policyEnvironmental policy is the commitment of an organization or government to the laws, regulations, and other policy mechanisms concerning environmental issues. These issues generally include air and water pollution, waste management, ecosystem management, maintenance of biodiversity, the management of natural resources, wildlife and endangered species. For example, concerning environmental policy, the implementation of an eco-energy-oriented policy at a global level to address the issues of global warming and climate changes could be addressed.
EpilimnionThe epilimnion or surface layer is the top-most layer in a thermally stratified lake. The epilimnion is the layer that is most affected by sunlight, its thermal energy heating the surface, thereby making it warmer and less dense. As a result, the epilimnion sits above the deeper metalimnion and hypolimnion, which are colder and denser. Additionally, the epilimnion is typically has a higher pH and higher dissolved oxygen concentration than the hypolimnion. In the water column, the epilimnion sits above all other layers.
Equilibrium constantThe equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical equilibrium, a state approached by a dynamic chemical system after sufficient time has elapsed at which its composition has no measurable tendency towards further change. For a given set of reaction conditions, the equilibrium constant is independent of the initial analytical concentrations of the reactant and product species in the mixture.
HypolimnionThe hypolimnion or under lake is the dense, bottom layer of water in a thermally-stratified lake. The word "hypolimnion" is derived from λιμνίον. It is the layer that lies below the thermocline. Typically the hypolimnion is the coldest layer of a lake in summer, and the warmest layer during winter. In deep, temperate lakes, the bottom-most waters of the hypolimnion are typically close to 4 °C throughout the year. The hypolimnion may be much warmer in lakes at warmer latitudes.
Lake stratificationLake stratification is the tendency of lakes to form separate and distinct thermal layers during warm weather. Typically stratified lakes show three distinct layers: the epilimnion, comprising the top warm layer; the thermocline (or metalimnion), the middle layer, whose depth may change throughout the day; and the colder hypolimnion, extending to the floor of the lake. Every lake has a set mixing regime that is influenced by lake morphometry and environmental conditions.
PondA pond is a small, still, land-based body of water formed by pooling inside a depression, either naturally or artificially. A pond is smaller than a lake and there are no official criteria distinguishing the two, although defining a pond to be less than in area, less than in depth and with less than 30% with emergent vegetation helps in distinguishing the ecology of ponds from those of lakes and wetlands. Ponds can be created by a wide variety of natural processes (e.g.
Grey box modelIn mathematics, statistics, and computational modelling, a grey box model combines a partial theoretical structure with data to complete the model. The theoretical structure may vary from information on the smoothness of results, to models that need only parameter values from data or existing literature. Thus, almost all models are grey box models as opposed to black box where no model form is assumed or white box models that are purely theoretical. Some models assume a special form such as a linear regression or neural network.
LakeA lake is a naturally occurring, relatively large body of water localized in a basin surrounded by dry land. A lake generally has a slower-moving flow than the inflow or outflow stream(s) that serve to feed or drain it. Lakes lie completely on land and are separate from the ocean, although, like the much larger oceans, they form part of the Earth's water cycle by serving as large standing pools of storage water. Most lakes are freshwater and account for almost all the world's surface freshwater, but some are salt lakes with salinities even higher than that of seawater.
Irreducible representationIn mathematics, specifically in the representation theory of groups and algebras, an irreducible representation or irrep of an algebraic structure is a nonzero representation that has no proper nontrivial subrepresentation , with closed under the action of . Every finite-dimensional unitary representation on a Hilbert space is the direct sum of irreducible representations. Irreducible representations are always indecomposable (i.e. cannot be decomposed further into a direct sum of representations), but the converse may not hold, e.
Representation theoryRepresentation theory is a branch of mathematics that studies abstract algebraic structures by representing their elements as linear transformations of vector spaces, and studies modules over these abstract algebraic structures. In essence, a representation makes an abstract algebraic object more concrete by describing its elements by matrices and their algebraic operations (for example, matrix addition, matrix multiplication).
Monomictic lakeMonomictic lakes are holomictic lakes that mix from top to bottom during one mixing period each year. Monomictic lakes may be subdivided into cold and warm types. Cold monomictic lakes are lakes that are covered by ice throughout much of the year. During their brief "summer", the surface waters remain at or below 4 °C. The ice prevents these lakes from mixing in winter. During summer, these lakes lack significant thermal stratification, and they mix thoroughly from top to bottom. These lakes are typical of cold-climate regions (e.
Elimination reactionAn elimination reaction is a type of organic reaction in which two substituents are removed from a molecule in either a one- or two-step mechanism. The one-step mechanism is known as the E2 reaction, and the two-step mechanism is known as the E1 reaction. The numbers refer not to the number of steps in the mechanism, but rather to the kinetics of the reaction: E2 is bimolecular (second-order) while E1 is unimolecular (first-order). In cases where the molecule is able to stabilize an anion but possesses a poor leaving group, a third type of reaction, E1CB, exists.
Gaussian eliminationIn mathematics, Gaussian elimination, also known as row reduction, is an algorithm for solving systems of linear equations. It consists of a sequence of operations performed on the corresponding matrix of coefficients. This method can also be used to compute the rank of a matrix, the determinant of a square matrix, and the inverse of an invertible matrix. The method is named after Carl Friedrich Gauss (1777–1855).
Lake ecosystemA lake ecosystem or lacustrine ecosystem includes biotic (living) plants, animals and micro-organisms, as well as abiotic (non-living) physical and chemical interactions. Lake ecosystems are a prime example of lentic ecosystems (lentic refers to stationary or relatively still freshwater, from the Latin lentus, which means "sluggish"), which include ponds, lakes and wetlands, and much of this article applies to lentic ecosystems in general. Lentic ecosystems can be compared with lotic ecosystems, which involve flowing terrestrial waters such as rivers and streams.
Dimictic lakeA dimictic lake is a body of freshwater whose difference in temperature between surface and bottom layers becomes negligible twice per year, allowing all strata of the lake's water to circulate vertically. All dimictic lakes are also considered holomictic, a category which includes all lakes which mix one or more times per year. During winter, dimictic lakes are covered by a layer of ice, creating a cold layer at the surface, a slightly warmer layer beneath the ice, and a still-warmer unfrozen bottom layer, while during summer, the same temperature-derived density differences separate the warm surface waters (the epilimnion), from the colder bottom waters (the hypolimnion).
