Molecular geometryMolecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths, bond angles, torsional angles and any other geometrical parameters that determine the position of each atom. Molecular geometry influences several properties of a substance including its reactivity, polarity, phase of matter, color, magnetism and biological activity. The angles between bonds that an atom forms depend only weakly on the rest of molecule, i.
Trigonal planar molecular geometryIn chemistry, trigonal planar is a molecular geometry model with one atom at the center and three atoms at the corners of an equilateral triangle, called peripheral atoms, all in one plane. In an ideal trigonal planar species, all three ligands are identical and all bond angles are 120°. Such species belong to the point group D3h. Molecules where the three ligands are not identical, such as , deviate from this idealized geometry. Examples of molecules with trigonal planar geometry include boron trifluoride (), formaldehyde (), phosgene (), and sulfur trioxide ().
Trigonal bipyramidal molecular geometryIn chemistry, a trigonal bipyramid formation is a molecular geometry with one atom at the center and 5 more atoms at the corners of a triangular bipyramid. This is one geometry for which the bond angles surrounding the central atom are not identical (see also pentagonal bipyramid), because there is no geometrical arrangement with five terminal atoms in equivalent positions. Examples of this molecular geometry are phosphorus pentafluoride (), and phosphorus pentachloride () in the gas phase.
Tetrahedral molecular geometryIn a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are cos−1(−) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane () as well as its heavier analogues. Methane and other perfectly symmetrical tetrahedral molecules belong to point group Td, but most tetrahedral molecules have lower symmetry. Tetrahedral molecules can be chiral.
Octahedral molecular geometryIn chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix octa. The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms. A perfect octahedron belongs to the point group Oh.
Pentagonal bipyramidal molecular geometryIn chemistry, a pentagonal bipyramid is a molecular geometry with one atom at the centre with seven ligands at the corners of a pentagonal bipyramid. A perfect pentagonal bipyramid belongs to the molecular point group D5h. The pentagonal bipyramid is a case where bond angles surrounding an atom are not identical (see also trigonal bipyramidal molecular geometry). This is one of the three common shapes for heptacoordinate transition metal complexes, along with the capped octahedron and the capped trigonal prism.
Square planar molecular geometryThe square planar molecular geometry in chemistry describes the stereochemistry (spatial arrangement of atoms) that is adopted by certain chemical compounds. As the name suggests, molecules of this geometry have their atoms positioned at the corners. Numerous compounds adopt this geometry, examples being especially numerous for transition metal complexes. The noble gas compound xenon tetrafluoride adopts this structure as predicted by VSEPR theory.
T-shaped molecular geometryIn chemistry, T-shaped molecular geometry describes the structures of some molecules where a central atom has three ligands. Ordinarily, three-coordinated compounds adopt trigonal planar or pyramidal geometries. Examples of T-shaped molecules are the halogen trifluorides, such as ClF3. According to VSEPR theory, T-shaped geometry results when three ligands and two lone pairs of electrons are bonded to the central atom, written in AXE notation as AX3E2.
TetrahedronIn geometry, a tetrahedron (plural: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular faces, six straight edges, and four vertex corners. The tetrahedron is the simplest of all the ordinary convex polyhedra. The tetrahedron is the three-dimensional case of the more general concept of a Euclidean simplex, and may thus also be called a 3-simplex. The tetrahedron is one kind of pyramid, which is a polyhedron with a flat polygon base and triangular faces connecting the base to a common point.
VSEPR theoryValence shell electron pair repulsion (VSEPR) theory (ˈvɛspər,_vəˈsɛpər , ), is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. It is also named the Gillespie-Nyholm theory after its two main developers, Ronald Gillespie and Ronald Nyholm. The premise of VSEPR is that the valence electron pairs surrounding an atom tend to repel each other. The greater the repulsion, the higher in energy (less stable) the molecule is.
Truncated tetrahedronIn geometry, the truncated tetrahedron is an Archimedean solid. It has 4 regular hexagonal faces, 4 equilateral triangle faces, 12 vertices and 18 edges (of two types). It can be constructed by truncating all 4 vertices of a regular tetrahedron at one third of the original edge length. A deeper truncation, removing a tetrahedron of half the original edge length from each vertex, is called rectification. The rectification of a tetrahedron produces an octahedron.
Triakis tetrahedronIn geometry, a triakis tetrahedron (or kistetrahedron) is a Catalan solid with 12 faces. Each Catalan solid is the dual of an Archimedean solid. The dual of the triakis tetrahedron is the truncated tetrahedron. The triakis tetrahedron can be seen as a tetrahedron with a triangular pyramid added to each face; that is, it is the Kleetope of the tetrahedron. It is very similar to the net for the 5-cell, as the net for a tetrahedron is a triangle with other triangles added to each edge, the net for the 5-cell a tetrahedron with pyramids attached to each face.
Orthocentric tetrahedronIn geometry, an orthocentric tetrahedron is a tetrahedron where all three pairs of opposite edges are perpendicular. It is also known as an orthogonal tetrahedron since orthogonal means perpendicular. It was first studied by Simon Lhuilier in 1782, and got the name orthocentric tetrahedron by G. de Longchamps in 1890. In an orthocentric tetrahedron the four altitudes are concurrent. This common point is called the orthocenter, and it has the property that it is the symmetric point of the center of the circumscribed sphere with respect to the centroid.
Goursat tetrahedronIn geometry, a Goursat tetrahedron is a tetrahedral fundamental domain of a Wythoff construction. Each tetrahedral face represents a reflection hyperplane on 3-dimensional surfaces: the 3-sphere, Euclidean 3-space, and hyperbolic 3-space. Coxeter named them after Édouard Goursat who first looked into these domains. It is an extension of the theory of Schwarz triangles for Wythoff constructions on the sphere. A Goursat tetrahedron can be represented graphically by a tetrahedral graph, which is in a dual configuration of the fundamental domain tetrahedron.
DisphenoidIn geometry, a disphenoid () is a tetrahedron whose four faces are congruent acute-angled triangles. It can also be described as a tetrahedron in which every two edges that are opposite each other have equal lengths. Other names for the same shape are isotetrahedron, sphenoid, bisphenoid, isosceles tetrahedron, equifacial tetrahedron, almost regular tetrahedron, and tetramonohedron. All the solid angles and vertex figures of a disphenoid are the same, and the sum of the face angles at each vertex is equal to two right angles.
OctahedronIn geometry, an octahedron () is a polyhedron with eight faces. The term is most commonly used to refer to the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet at each vertex. A regular octahedron is the dual polyhedron of a cube. It is a rectified tetrahedron. It is a square bipyramid in any of three orthogonal orientations. It is also a triangular antiprism in any of four orientations. An octahedron is the three-dimensional case of the more general concept of a cross polytope.
Hydrogen atomA hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen constitutes about 75% of the baryonic mass of the universe. In everyday life on Earth, isolated hydrogen atoms (called "atomic hydrogen") are extremely rare. Instead, a hydrogen atom tends to combine with other atoms in compounds, or with another hydrogen atom to form ordinary (diatomic) hydrogen gas, H2.
Truncated octahedronIn geometry, the truncated octahedron is the Archimedean solid that arises from a regular octahedron by removing six pyramids, one at each of the octahedron's vertices. The truncated octahedron has 14 faces (8 regular hexagons and 6 squares), 36 edges, and 24 vertices. Since each of its faces has point symmetry the truncated octahedron is a 6-zonohedron. It is also the Goldberg polyhedron GIV(1,1), containing square and hexagonal faces. Like the cube, it can tessellate (or "pack") 3-dimensional space, as a permutohedron.
Hydrogen-like atomA hydrogen-like atom (or hydrogenic atom) is any atom or ion with a single valence electron. These atoms are isoelectronic with hydrogen. Examples of hydrogen-like atoms include, but are not limited to, hydrogen itself, all alkali metals such as Rb and Cs, singly ionized alkaline earth metals such as Ca+ and Sr+ and other ions such as He+, Li2+, and Be3+ and isotopes of any of the above. A hydrogen-like atom includes a positively charged core consisting of the atomic nucleus and any core electrons as well as a single valence electron.
List of uniform polyhedraIn geometry, a uniform polyhedron is a polyhedron which has regular polygons as faces and is vertex-transitive (transitive on its vertices, isogonal, i.e. there is an isometry mapping any vertex onto any other). It follows that all vertices are congruent, and the polyhedron has a high degree of reflectional and rotational symmetry. Uniform polyhedra can be divided between convex forms with convex regular polygon faces and star forms. Star forms have either regular star polygon faces or vertex figures or both.
