Lecture

Nucleation and Growth: Interfacial Phenomena

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In course

MSE-304: Surfaces and interfaces

This lecture introduces the fundamental concepts for describing, characterizing, and engineering surfaces and interfaces. Students will develop both theoretical and practical understanding of how interfacial phenomena influence surface properties and techn ...

Description

This lecture covers the concepts of nucleation and growth, Ostwald ripening, LaPlace pressure, and Kelvin equation. It explains the phase equilibrium in multi-phase systems, the chemical potential of phases of finite size, and the size dependence of generic phase transitions. The instructor discusses the critical micelle concentration, self-assembly, and the temperature dependence of nucleation rate. The lecture also delves into the heterogeneous nucleation at interfaces and the melting point depression phenomenon.

Instructors (2)

Francesco Stellacci

Francesco Stellacci graduated in Materials Engineering at the Politecnico di Milano in 1998 with a thesis on photochromic polymers with Prof. Giuseppe Zerbi and Mariacarla Gallazzi. In 1999 he moved to the Chemistry Department of the University of Arizona for as a post-doc in the group of Joe Perry in close collaboration with the group of Seth Marder. In 2002 he moved to the Department of Materials Science and Engineering at the Massachusetts Institute of Technology as an assistant professor. He was then promoted to associate without (2006) and with tenure (2009). In 2010 he moved to the Institute of Materials at EPFL as a full Professor. He holds the Alcan EP Chair. Francesco was one of the recipients of the Technology Review TR35 "35 Innovator under 35" award in 2005, and the Popular Science Magazine "Brilliant 10" award in 2007. He has been a Packard Fellow starting 2005.

Nako Nakatsuka

Mission At the Laboratory of Chemical Nanotechnology (CHEMINA), our mission is to develop translational chemical biosensing technologies that advance human health. Working at the intersection of chemistry, engineering, and neuroscience, we seek to probe the dynamic chemical landscape of biological systems across in vitro systems, in vivo models, and human clinical samples. We develop novel biorecognition elements and innovate biosensing platforms to enable monitoring of small molecules in complex biofluids,

Official source

Ontological neighbourhood

Physics

Condensed matter physics: Phase transitions

Related concepts (32)

Nucleation

In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled (at atmospheric pressure) below 0 °C, it will tend to freeze into ice, but volumes of water cooled only a few degrees below 0 °C often stay completely free of ice for long periods (supercooling).

Phase diagram

A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, volume, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium. Common components of a phase diagram are lines of equilibrium or phase boundaries, which refer to lines that mark conditions under which multiple phases can coexist at equilibrium. Phase transitions occur along lines of equilibrium.

Economic growth

Economic growth can be defined as the increase or improvement in the inflation-adjusted market value of the goods and services produced by an economy in a financial year. Statisticians conventionally measure such growth as the percent rate of increase in the real and nominal gross domestic product (GDP). Growth is usually calculated in real terms – i.e., inflation-adjusted terms – to eliminate the distorting effect of inflation on the prices of goods produced. Measurement of economic growth uses national income accounting.

Post-growth

Post-growth is a stance on economic growth concerning the limits-to-growth dilemma — recognition that, on a planet of finite material resources, extractive economies and populations cannot grow infinitely. The term "post-growth" acknowledges that economic growth can generate beneficial effects up to a point, but beyond that point (cited as $25,000 GDP/capita by Richard Wilkinson and Kate Pickett in their book The Spirit Level) it is necessary to look for other indicators and techniques to increase human wellbeing.

Phase (matter)

In the physical sciences, a phase is a region of material that is chemically uniform, physically distinct, and (often) mechanically separable. In a system consisting of ice and water in a glass jar, the ice cubes are one phase, the water is a second phase, and the humid air is a third phase over the ice and water. The glass of the jar is another separate phase. (See .) More precisely, a phase is a region of space (a thermodynamic system), throughout which all physical properties of a material are essentially uniform.

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