Endothermic processIn thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy H (or internal energy U) of the system. In such a process, a closed system usually absorbs thermal energy from its surroundings, which is heat transfer into the system. Thus, an endothermic reaction generally leads to an increase in the temperature of the system and a decrease in that of the surroundings. It may be a chemical process, such as dissolving ammonium nitrate () in water (), or a physical process, such as the melting of ice cubes.
Third law of thermodynamicsThe third law of thermodynamics states that the entropy of a closed system at thermodynamic equilibrium approaches a constant value when its temperature approaches absolute zero. This constant value cannot depend on any other parameters characterizing the system, such as pressure or applied magnetic field. At absolute zero (zero kelvins) the system must be in a state with the minimum possible energy. Entropy is related to the number of accessible microstates, and there is typically one unique state (called the ground state) with minimum energy.
Enthalpy of mixingIn thermodynamics, the enthalpy of mixing (also heat of mixing and excess enthalpy) is the enthalpy liberated or absorbed from a substance upon mixing. When a substance or compound is combined with any other substance or compound, the enthalpy of mixing is the consequence of the new interactions between the two substances or compounds. This enthalpy, if released exothermically, can in an extreme case cause an explosion. Enthalpy of mixing can often be ignored in calculations for mixtures where other heat terms exist, or in cases where the mixture is ideal.
Thermodynamic databases for pure substancesThermodynamic databases contain information about thermodynamic properties for substances, the most important being enthalpy, entropy, and Gibbs free energy. Numerical values of these thermodynamic properties are collected as tables or are calculated from thermodynamic datafiles. Data is expressed as temperature-dependent values for one mole of substance at the standard pressure of 101.325 kPa (1 atm), or 100 kPa (1 bar). Both of these definitions for the standard condition for pressure are in use.
Helmholtz free energyIn thermodynamics, the Helmholtz free energy (or Helmholtz energy) is a thermodynamic potential that measures the useful work obtainable from a closed thermodynamic system at a constant temperature (isothermal). The change in the Helmholtz energy during a process is equal to the maximum amount of work that the system can perform in a thermodynamic process in which temperature is held constant. At constant temperature, the Helmholtz free energy is minimized at equilibrium.
Endergonic reactionIn chemical thermodynamics, an endergonic reaction (; also called a heat absorbing nonspontaneous reaction or an unfavorable reaction) is a chemical reaction in which the standard change in free energy is positive, and an additional driving force is needed to perform this reaction. In layman's terms, the total amount of useful energy is negative (it takes more energy to start the reaction than what is received out of it) so the total energy is a net negative result, as opposed to a net positive result in an exergonic reaction.
Standard molar entropyIn chemistry, the standard molar entropy is the entropy content of one mole of pure substance at a standard state of pressure and any temperature of interest. These are often (but not necessarily) chosen to be the standard temperature and pressure. The standard molar entropy at pressure = is usually given the symbol S°, and has units of joules per mole per kelvin (J⋅mol−1⋅K−1). Unlike standard enthalpies of formation, the value of S° is absolute. That is, an element in its standard state has a definite, nonzero value of S at room temperature.
Timeline of thermodynamicsA timeline of events in the history of thermodynamics. 1650 – Otto von Guericke builds the first vacuum pump 1660 – Robert Boyle experimentally discovers Boyle's Law, relating the pressure and volume of a gas (published 1662) 1665 – Robert Hooke published his book Micrographia, which contained the statement: "Heat being nothing else but a very brisk and vehement agitation of the parts of a body." 1667 – J. J. Becher puts forward a theory of combustion involving combustible earth in his book Physica subterranea (see Phlogiston theory).
Phase transitionIn chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter: solid, liquid, and gas, and in rare cases, plasma. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change as a result of the change of external conditions, such as temperature or pressure.
Enthalpy of vaporizationIn thermodynamics, the enthalpy of vaporization (symbol ∆Hvap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy (enthalpy) that must be added to a liquid substance to transform a quantity of that substance into a gas. The enthalpy of vaporization is a function of the pressure at which the transformation (vaporization or evaporation) takes place. The enthalpy of vaporization is often quoted for the normal boiling temperature of the substance.
Chemical reactionA chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur.
Enthalpy of fusionIn thermodynamics, the enthalpy of fusion of a substance, also known as (latent) heat of fusion, is the change in its enthalpy resulting from providing energy, typically heat, to a specific quantity of the substance to change its state from a solid to a liquid, at constant pressure. It is the amount of energy required to convert one mole of solid into liquid. For example, when melting 1 kg of ice (at 0 °C under a ), 333.55 kJ of energy is absorbed with no temperature change.
