HeteroatomIn chemistry, a heteroatom () is, strictly, any atom that is not carbon or hydrogen. In practice, the term is usually used more specifically to indicate that non-carbon atoms have replaced carbon in the backbone of the molecular structure. Typical heteroatoms are nitrogen (N), oxygen (O), sulfur (S), phosphorus (P), chlorine (Cl), bromine (Br), and iodine (I), as well as the metals lithium (Li) and magnesium (Mg). It can also be used with highly specific meanings in specialised contexts.
Ring strainIn organic chemistry, ring strain is a type of instability that exists when bonds in a molecule form angles that are abnormal. Strain is most commonly discussed for small rings such as cyclopropanes and cyclobutanes, whose internal angles are substantially smaller than the idealized value of approximately 109°. Because of their high strain, the heat of combustion for these small rings is elevated. Ring strain results from a combination of angle strain, conformational strain or Pitzer strain (torsional eclipsing interactions), and transannular strain, also known as van der Waals strain or Prelog strain.
Rings of SaturnThe rings of Saturn are the most extensive ring system of any planet in the Solar System. They consist of countless small particles, ranging in size from micrometers to meters, that orbit around Saturn. The ring particles are made almost entirely of water ice, with a trace component of rocky material. There is still no consensus as to their mechanism of formation. Although theoretical models indicated that the rings were likely to have formed early in the Solar System's history, newer data from Cassini suggested they formed relatively late.
Cyclic compoundA cyclic compound (or ring compound) is a term for a compound in the field of chemistry in which one or more series of atoms in the compound is connected to form a ring. Rings may vary in size from three to many atoms, and include examples where all the atoms are carbon (i.e., are carbocycles), none of the atoms are carbon (inorganic cyclic compounds), or where both carbon and non-carbon atoms are present (heterocyclic compounds with rings containing both carbon and non-carbon).
Rings of JupiterThe planet Jupiter has a system of faint planetary rings. The Jovian rings were the third ring system to be discovered in the Solar System, after those of Saturn and Uranus. The main ring was discovered in 1979 by the Voyager 1 space probe and the system was more thoroughly investigated in the 1990s by the Galileo orbiter. The main ring has also been observed by the Hubble Space Telescope and from Earth for several years. Ground-based observation of the rings requires the largest available telescopes.
Mirror imageA mirror image (in a plane mirror) is a reflected duplication of an object that appears almost identical, but is reversed in the direction perpendicular to the mirror surface. As an optical effect it results from reflection off from substances such as a mirror or water. It is also a concept in geometry and can be used as a conceptualization process for 3-D structures. Reflectional symmetry In geometry, the mirror image of an object or two-dimensional figure is the formed by reflection in a plane mirror; it is of the same size as the original object, yet different, unless the object or figure has reflection symmetry (also known as a P-symmetry).
IsomerIn chemistry, isomers are molecules or polyatomic ions with identical molecular formula – that is, same number of atoms of each element – but distinct arrangements of atoms in space. Isomerism refers to the existence or possibility of isomers. Isomers do not necessarily share similar chemical or physical properties. Two main forms of isomerism are structural or constitutional isomerism, in which bonds between the atoms differ; and stereoisomerism or spatial isomerism, in which the bonds are the same but the relative positions of the atoms differ.
Ring (mathematics)In mathematics, rings are algebraic structures that generalize fields: multiplication need not be commutative and multiplicative inverses need not exist. In other words, a ring is a set equipped with two binary operations satisfying properties analogous to those of addition and multiplication of integers. Ring elements may be numbers such as integers or complex numbers, but they may also be non-numerical objects such as polynomials, square matrices, functions, and power series.
Quotient ringIn ring theory, a branch of abstract algebra, a quotient ring, also known as factor ring, difference ring or residue class ring, is a construction quite similar to the quotient group in group theory and to the quotient space in linear algebra. It is a specific example of a quotient, as viewed from the general setting of universal algebra. Starting with a ring R and a two-sided ideal I in R, a new ring, the quotient ring R / I, is constructed, whose elements are the cosets of I in R subject to special + and ⋅ operations.
Artinian ringIn mathematics, specifically abstract algebra, an Artinian ring (sometimes Artin ring) is a ring that satisfies the descending chain condition on (one-sided) ideals; that is, there is no infinite descending sequence of ideals. Artinian rings are named after Emil Artin, who first discovered that the descending chain condition for ideals simultaneously generalizes finite rings and rings that are finite-dimensional vector spaces over fields.
Local ringIn mathematics, more specifically in ring theory, local rings are certain rings that are comparatively simple, and serve to describe what is called "local behaviour", in the sense of functions defined on varieties or manifolds, or of algebraic number fields examined at a particular place, or prime. Local algebra is the branch of commutative algebra that studies commutative local rings and their modules. In practice, a commutative local ring often arises as the result of the localization of a ring at a prime ideal.
Eclipsed conformationIn chemistry an eclipsed conformation is a conformation in which two substituents X and Y on adjacent atoms A, B are in closest proximity, implying that the torsion angle X–A–B–Y is 0°. Such a conformation can exist in any open chain, single chemical bond connecting two sp3-hybridised atoms, and it is normally a conformational energy maximum. This maximum is often explained by steric hindrance, but its origins sometimes actually lie in hyperconjugation (as when the eclipsing interaction is of two hydrogen atoms).
