Lecture

Anomalous Sorption: Engineered Calcium Silicate Hydrates in Cementitious Materials

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Description

This lecture with Ippei Maruyama explores the microstructural changes in cementitious materials due to sorption and transport phenomena, focusing on the evolution of interlayer water, gel pore water, and interhydrate pores. The presentation covers measurements using 1H-NMR relaxometry, long-term length change isotherms, and short-term length change isotherms. Results show the evolution of evaporable water, shrinkage strain, and the impact of drying conditions on the material's properties.

In MOOC

Sorption and transport in cementitious materials

In the MOOC: “Cement chemistry and sustainable cementitious materials”; you learned how to create more sustainable cementitious materials. But concrete is not an inert rock. It is a dynamic porous material, which can exchange water, gas and ions with its environment. Through physical and chemical interactions, these exchanges can have dramatic consequences: cracks due to shrinkage, reinforcement bars corrosion, spalling, … For a true sustainability, the durability of cementitious materials should not be f

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Related concepts (4)

Sorption

Sorption is a physical and chemical process by which one substance becomes attached to another. Specific cases of sorption are treated in the following articles: Absorption "the incorporation of a substance in one state into another of a different state" (e.g., liquids being absorbed by a solid or gases being absorbed by a liquid); Adsorption The physical adherence or bonding of ions and molecules onto the surface of another phase (e.g.

Adsorption

Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the adsorbate on the surface of the adsorbent. This process differs from absorption, in which a fluid (the absorbate) is dissolved by or permeates a liquid or solid (the absorbent). Adsorption is a surface phenomenon and the adsorbate does not penetrate through the surface and into the bulk of the adsorbent, while absorption involves transfer of the absorbate into the volume of the material, although adsorption does often precede absorption.

Transport phenomena

In engineering, physics, and chemistry, the study of transport phenomena concerns the exchange of mass, energy, charge, momentum and angular momentum between observed and studied systems. While it draws from fields as diverse as continuum mechanics and thermodynamics, it places a heavy emphasis on the commonalities between the topics covered. Mass, momentum, and heat transport all share a very similar mathematical framework, and the parallels between them are exploited in the study of transport phenomena to draw deep mathematical connections that often provide very useful tools in the analysis of one field that are directly derived from the others.

Chemical engineering

Chemical engineering is an engineering field which deals with the study of operation and design of chemical plants as well as methods of improving production. Chemical engineers develop economical commercial processes to convert raw materials into useful products. Chemical engineering uses principles of chemistry, physics, mathematics, biology, and economics to efficiently use, produce, design, transport and transform energy and materials.

Related concepts (4)