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Lecture

Glass Durability

In course

MSE-171: Materials

Une introduction à la science des matériaux appliquée aux matériaux de construction courants, en particulier le béton et les métaux. Description de leur fabrication, leurs comportements mécanique et thermique et leur utilisation en construction. ...

Description

This lecture covers the topic of glass durability, explaining how glass can degrade over time due to various mechanisms such as reactions with water and hydrolysis, leading to a decrease in transparency and potential dissolution. The instructor details the chemical processes involved, highlighting the importance of protecting glass from basic substances to prevent degradation.

Instructors (6)

Lionel Sofia

Cyril Henri Dénéréaz

Emmanuelle Anne Boehm Courjault

Karen Scrivener

De nationalité anglaise, Karen Scrivener est née en 1958. Au cours de sa carrière, ses travaux et sa recherche traitaient des domaines suivants: Identification du développement microstucturale pendant l'hydratation du ciment. Elaboration d'une approche multitechnique pour étudier la microstucture des ciments et bétons, avec accent sur la quantification par analyse des images d'électrons retrodiffusés. Caractérisation de l'auréole de transition de la pâte de ciment autour des granulats. Compréhension des processus de dégardation des bétons, en particulier le gonflement lié à la formation de l'éttringite retardée dans les bétons étuvés.

Julie Nathalie S Gheysen

Jean-Marie Drezet

1992-1996: PhD work at Laboratoire de Métallurgie Physique under the supervision of Prof. Michel Rappaz (cf : http://library.epfl.ch/theses/?display=detail&nr=1509) 1997-2000: EMPACT project (European Modelling Programme for Aluminium Casting Technologies) 2001-2004: VIRCAST project (European Virtual Casting) 2005-2006: Study of the sawing process of rolling sheet al. ingots (Alcan Fonds) 2005-2006: WelAIR project (Welding of Airframes, EADS) 2005-2008: study of the electron beam welding of Cu-Cr-Zr alloys (CEA, France) 2006-2008: study of the laser beam welding of Al-Li alloys (EADS, France) 2008-2011: co-supervision with Prof. A. Nussbaumer of the PhD work of C. Acevedo on the influence of residual stresses on the fatigue design of tubular welded joints, http://library.epfl.ch/theses/?nr=5056 2007-2010: co-supervision with Prof. J.-F. Molinari of the PhD work of K. Shahim on the Normal Pressure Hydrocephalus (S. Momjian, HU-Genève et R. Sinkus, ESPCI-Paris), http://library.epfl.ch/theses/?nr=5191 2008-2012: co-supervision with Prof. M. Rappaz of the PhD work of M. Sistaninia on the simulation of solidification cracking using granular models (CCMX-MERU project) 2010-2014: supervision with Prof. M. Rappaz of the PhD work of N. Chobaut on the modelling of stresses during quenching of thick heat treatable aluminium parts (CCMX-MERU project) 2011-2015: supervision with Prof. H. Van Swygenhoven-Moens of the PhD work of P. Schloth on precipitation during quenching of thick heat treatable aluminium parts (CCMX-MERU project)

Official source

Related concepts (5)

Chemical reaction

A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur.

Reaction mechanism

In chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs. A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of an overall chemical reaction. The detailed steps of a reaction are not observable in most cases. The conjectured mechanism is chosen because it is thermodynamically feasible and has experimental support in isolated intermediates (see next section) or other quantitative and qualitative characteristics of the reaction.

Reaction intermediate

In chemistry, a reaction intermediate or an intermediate is a molecular entity that is formed from the reactants (or preceding intermediates) but is consumed in further reactions in stepwise chemical reactions that contain multiple elementary steps. Intermediates are the reaction product of one elementary step, but do not appear in the chemical equation for an overall chemical equation. For example, consider this hypothetical stepwise reaction: A + B -> C + D The reaction includes two elementary steps: A + B -> X X -> C + D In this example, X is a reaction intermediate.

Non-covalent interaction

In chemistry, a non-covalent interaction differs from a covalent bond in that it does not involve the sharing of electrons, but rather involves more dispersed variations of electromagnetic interactions between molecules or within a molecule. The chemical energy released in the formation of non-covalent interactions is typically on the order of 1–5 kcal/mol (1000–5000 calories per 6.02 molecules). Non-covalent interactions can be classified into different categories, such as electrostatic, π-effects, van der Waals forces, and hydrophobic effects.

Protein–protein interaction

Protein–protein interactions (PPIs) are physical contacts of high specificity established between two or more protein molecules as a result of biochemical events steered by interactions that include electrostatic forces, hydrogen bonding and the hydrophobic effect. Many are physical contacts with molecular associations between chains that occur in a cell or in a living organism in a specific biomolecular context. Proteins rarely act alone as their functions tend to be regulated.

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