Group representationIn the mathematical field of representation theory, group representations describe abstract groups in terms of bijective linear transformations of a vector space to itself (i.e. vector space automorphisms); in particular, they can be used to represent group elements as invertible matrices so that the group operation can be represented by matrix multiplication. In chemistry, a group representation can relate mathematical group elements to symmetric rotations and reflections of molecules.
Conjugacy classIn mathematics, especially group theory, two elements and of a group are conjugate if there is an element in the group such that This is an equivalence relation whose equivalence classes are called conjugacy classes. In other words, each conjugacy class is closed under for all elements in the group. Members of the same conjugacy class cannot be distinguished by using only the group structure, and therefore share many properties. The study of conjugacy classes of non-abelian groups is fundamental for the study of their structure.
Hamiltonian mechanicsHamiltonian mechanics emerged in 1833 as a reformulation of Lagrangian mechanics. Introduced by Sir William Rowan Hamilton, Hamiltonian mechanics replaces (generalized) velocities used in Lagrangian mechanics with (generalized) momenta. Both theories provide interpretations of classical mechanics and describe the same physical phenomena. Hamiltonian mechanics has a close relationship with geometry (notably, symplectic geometry and Poisson structures) and serves as a link between classical and quantum mechanics.
Character theoryIn mathematics, more specifically in group theory, the character of a group representation is a function on the group that associates to each group element the trace of the corresponding matrix. The character carries the essential information about the representation in a more condensed form. Georg Frobenius initially developed representation theory of finite groups entirely based on the characters, and without any explicit matrix realization of representations themselves.
Character tableIn group theory, a branch of abstract algebra, a character table is a two-dimensional table whose rows correspond to irreducible representations, and whose columns correspond to conjugacy classes of group elements. The entries consist of characters, the traces of the matrices representing group elements of the column's class in the given row's group representation. In chemistry, crystallography, and spectroscopy, character tables of point groups are used to classify e.g.
Hamiltonian systemA Hamiltonian system is a dynamical system governed by Hamilton's equations. In physics, this dynamical system describes the evolution of a physical system such as a planetary system or an electron in an electromagnetic field. These systems can be studied in both Hamiltonian mechanics and dynamical systems theory. Informally, a Hamiltonian system is a mathematical formalism developed by Hamilton to describe the evolution equations of a physical system.
Representation theory of finite groupsThe representation theory of groups is a part of mathematics which examines how groups act on given structures. Here the focus is in particular on operations of groups on vector spaces. Nevertheless, groups acting on other groups or on sets are also considered. For more details, please refer to the section on permutation representations. Other than a few marked exceptions, only finite groups will be considered in this article. We will also restrict ourselves to vector spaces over fields of characteristic zero.
Hamiltonian pathIn the mathematical field of graph theory, a Hamiltonian path (or traceable path) is a path in an undirected or directed graph that visits each vertex exactly once. A Hamiltonian cycle (or Hamiltonian circuit) is a cycle that visits each vertex exactly once. A Hamiltonian path that starts and ends at adjacent vertices can be completed by adding one more edge to form a Hamiltonian cycle, and removing any edge from a Hamiltonian cycle produces a Hamiltonian path.
Mathematical formulation of quantum mechanicsThe mathematical formulations of quantum mechanics are those mathematical formalisms that permit a rigorous description of quantum mechanics. This mathematical formalism uses mainly a part of functional analysis, especially Hilbert spaces, which are a kind of linear space. Such are distinguished from mathematical formalisms for physics theories developed prior to the early 1900s by the use of abstract mathematical structures, such as infinite-dimensional Hilbert spaces (L2 space mainly), and operators on these spaces.
Schur's lemmaIn mathematics, Schur's lemma is an elementary but extremely useful statement in representation theory of groups and algebras. In the group case it says that if M and N are two finite-dimensional irreducible representations of a group G and φ is a linear map from M to N that commutes with the action of the group, then either φ is invertible, or φ = 0. An important special case occurs when M = N, i.e. φ is a self-map; in particular, any element of the center of a group must act as a scalar operator (a scalar multiple of the identity) on M.
Quantum mechanicsQuantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales.
Hamiltonian path problemIn the mathematical field of graph theory the Hamiltonian path problem and the Hamiltonian cycle problem are problems of determining whether a Hamiltonian path (a path in an undirected or directed graph that visits each vertex exactly once) or a Hamiltonian cycle exists in a given graph (whether directed or undirected). Both problems are NP-complete.
Hamiltonian field theoryIn theoretical physics, Hamiltonian field theory is the field-theoretic analogue to classical Hamiltonian mechanics. It is a formalism in classical field theory alongside Lagrangian field theory. It also has applications in quantum field theory. The Hamiltonian for a system of discrete particles is a function of their generalized coordinates and conjugate momenta, and possibly, time. For continua and fields, Hamiltonian mechanics is unsuitable but can be extended by considering a large number of point masses, and taking the continuous limit, that is, infinitely many particles forming a continuum or field.
Control characterIn computing and telecommunication, a control character or non-printing character (NPC) is a code point in a character set that does not represent a written character or symbol. They are used as in-band signaling to cause effects other than the addition of a symbol to the text. All other characters are mainly graphic characters, also known as printing characters (or printable characters), except perhaps for "space" characters. In the ASCII standard there are 33 control characters, such as code 7, , which rings a terminal bell.
Measurement in quantum mechanicsIn quantum physics, a measurement is the testing or manipulation of a physical system to yield a numerical result. A fundamental feature of quantum theory is that the predictions it makes are probabilistic. The procedure for finding a probability involves combining a quantum state, which mathematically describes a quantum system, with a mathematical representation of the measurement to be performed on that system. The formula for this calculation is known as the Born rule.
Character (arts)In fiction, a character is a person or other being in a narrative (such as a novel, play, radio or television series, music, film, or video game). The character may be entirely fictional or based on a real-life person, in which case the distinction of a "fictional" versus "real" character may be made. Derived from the Ancient Greek word χαρακτήρ, the English word dates from the Restoration, although it became widely used after its appearance in Tom Jones by Henry Fielding in 1749.
Class functionIn mathematics, especially in the fields of group theory and representation theory of groups, a class function is a function on a group G that is constant on the conjugacy classes of G. In other words, it is invariant under the conjugation map on G. Such functions play a basic role in representation theory. The character of a linear representation of G over a field K is always a class function with values in K. The class functions form the center of the group ring K[G]. Here a class function f is identified with the element .
SymmetrySymmetry () in everyday language refers to a sense of harmonious and beautiful proportion and balance. In mathematics, the term has a more precise definition and is usually used to refer to an object that is invariant under some transformations, such as translation, reflection, rotation, or scaling. Although these two meanings of the word can sometimes be told apart, they are intricately related, and hence are discussed together in this article.
Representation theory of the symmetric groupIn mathematics, the representation theory of the symmetric group is a particular case of the representation theory of finite groups, for which a concrete and detailed theory can be obtained. This has a large area of potential applications, from symmetric function theory to quantum chemistry studies of atoms, molecules and solids. The symmetric group Sn has order n!. Its conjugacy classes are labeled by partitions of n.
Hamiltonian (quantum mechanics)In quantum mechanics, the Hamiltonian of a system is an operator corresponding to the total energy of that system, including both kinetic energy and potential energy. Its spectrum, the system's energy spectrum or its set of energy eigenvalues, is the set of possible outcomes obtainable from a measurement of the system's total energy. Due to its close relation to the energy spectrum and time-evolution of a system, it is of fundamental importance in most formulations of quantum theory.
