Geometric seriesIn mathematics, a geometric series is the sum of an infinite number of terms that have a constant ratio between successive terms. For example, the series is geometric, because each successive term can be obtained by multiplying the previous term by . In general, a geometric series is written as , where is the coefficient of each term and is the common ratio between adjacent terms.
CW complexA CW complex (also called cellular complex or cell complex) is a kind of a topological space that is particularly important in algebraic topology. It was introduced by J. H. C. Whitehead to meet the needs of homotopy theory. This class of spaces is broader and has some better properties than simplicial complexes, but still retains a combinatorial nature that allows for computation (often with a much smaller complex). The C stands for "closure-finite", and the W for "weak" topology.
Chain complexIn mathematics, a chain complex is an algebraic structure that consists of a sequence of abelian groups (or modules) and a sequence of homomorphisms between consecutive groups such that the of each homomorphism is included in the kernel of the next. Associated to a chain complex is its homology, which describes how the images are included in the kernels. A cochain complex is similar to a chain complex, except that its homomorphisms are in the opposite direction. The homology of a cochain complex is called its cohomology.
Coordination complexA coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals (elements like titanium that belong to the periodic table's d-block), are coordination complexes. Coordination complexes are so pervasive that their structures and reactions are described in many ways, sometimes confusingly.
Metal-phosphine complexA metal-phosphine complex is a coordination complex containing one or more phosphine ligands. Almost always, the phosphine is an organophosphine of the type R3P (R = alkyl, aryl). Metal phosphine complexes are useful in homogeneous catalysis. Prominent examples of metal phosphine complexes include Wilkinson's catalyst (Rh(PPh3)3Cl), Grubbs' catalyst, and tetrakis(triphenylphosphine)palladium(0). Many metal phosphine complexes are prepared by reactions of metal halides with preformed phosphines.
NumberA number is a mathematical object used to count, measure, and label. The original examples are the natural numbers 1, 2, 3, 4, and so forth. Numbers can be represented in language with number words. More universally, individual numbers can be represented by symbols, called numerals; for example, "5" is a numeral that represents the number five. As only a relatively small number of symbols can be memorized, basic numerals are commonly organized in a numeral system, which is an organized way to represent any number.
PiThe number pi (paɪ; spelled out as "pi") is a mathematical constant that is the ratio of a circle's circumference to its diameter, approximately equal to 3.14159. The number pi appears in many formulae across mathematics and physics. It is an irrational number, meaning that it cannot be expressed exactly as a ratio of two integers, although fractions such as are commonly used to approximate it. Consequently, its decimal representation never ends, nor enters a permanently repeating pattern.
Leibniz formula for πIn mathematics, the Leibniz formula for pi, named after Gottfried Wilhelm Leibniz, states that an alternating series. It is sometimes called the Madhava–Leibniz series as it was first discovered by the Indian mathematician Madhava of Sangamagrama or his followers in the 14th–15th century (see Madhava series), and was later independently rediscovered by James Gregory in 1671 and Leibniz in 1673.
Proof that π is irrationalIn the 1760s, Johann Heinrich Lambert was the first to prove that the number pi is irrational, meaning it cannot be expressed as a fraction , where and are both integers. In the 19th century, Charles Hermite found a proof that requires no prerequisite knowledge beyond basic calculus. Three simplifications of Hermite's proof are due to Mary Cartwright, Ivan Niven, and Nicolas Bourbaki. Another proof, which is a simplification of Lambert's proof, is due to Miklós Laczkovich. Many of these are proofs by contradiction.
