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Lecture

Optical Methods in Chemistry: Materials Properties and Applications

In course

CH-417: Optical methods in chemistry

Introduction and application of photon based tools for chemical sciences: from basic concepts to optical and x-ray lasers ...

Description

This lecture covers optical methods in chemistry, focusing on materials properties and applications. Topics include electromagnetic waves in dielectric media, optical constants of various materials, dispersion, second and third-order non-linear optics, and self-focusing phenomena. The instructor discusses the Kramers-Kronig relation, susceptibility in different media, and examples of second and third harmonic generation. Additionally, the lecture explores optical parametric devices, the optical Kerr effect, and self-phase modulation. The session concludes with a detailed explanation of the relationship between polarization density and electric field in non-linear optics.

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Instructor

Christoph Bostedt

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Related concepts (32)

Nonlinear optics

Nonlinear optics (NLO) is the branch of optics that describes the behaviour of light in nonlinear media, that is, media in which the polarization density P responds non-linearly to the electric field E of the light. The non-linearity is typically observed only at very high light intensities (when the electric field of the light is >108 V/m and thus comparable to the atomic electric field of ~1011 V/m) such as those provided by lasers. Above the Schwinger limit, the vacuum itself is expected to become nonlinear.

Dispersion (optics)

In optics and in wave propagation in general, dispersion is the phenomenon in which the phase velocity of a wave depends on its frequency; sometimes the term chromatic dispersion is used for specificity to optics in particular. A medium having this common property may be termed a dispersive medium (plural dispersive media). Although the term is used in the field of optics to describe light and other electromagnetic waves, dispersion in the same sense can apply to any sort of wave motion such as acoustic dispersion in the case of sound and seismic waves, and in gravity waves (ocean waves).

Optics

Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultraviolet, and infrared light. Because light is an electromagnetic wave, other forms of electromagnetic radiation such as X-rays, microwaves, and radio waves exhibit similar properties.

Electric field

An electric field (sometimes E-field) is the physical field that surrounds electrically charged particles and exerts force on all other charged particles in the field, either attracting or repelling them. It also refers to the physical field for a system of charged particles. Electric fields originate from electric charges and time-varying electric currents. Electric fields and magnetic fields are both manifestations of the electromagnetic field, one of the four fundamental interactions (also called forces) of nature.

Second-harmonic generation

Second-harmonic generation (SHG, also called frequency doubling) is a nonlinear optical process in which two photons with the same frequency interact with a nonlinear material, are "combined", and generate a new photon with twice the energy of the initial photons (equivalently, twice the frequency and half the wavelength), that conserves the coherence of the excitation. It is a special case of sum-frequency generation (2 photons), and more generally of harmonic generation.

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