Lecture

First Law of Thermodynamics: Energy Conservation and Work Calculation

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In course

PHYS-106(h): General physics : thermodynamics

Le but du cours de Physique générale est de donner à l'étudiant les notions de base nécessaires à la compréhension des phénomènes physiques. L'objectif est atteint lorsque l'étudiant est capable de prévoir quantitativement les conséquences de ces phénomène ...

Description

This lecture covers the first law of thermodynamics, describing it as inspired by the conservation of energy in mechanics. It explains the different quantities defined in the first principles, focusing on the sign convention. The lecture delves into thermodynamic transformations, the calculation of work done or received by a system, and the importance of energy conservation. It also discusses the generalization of the conservation of energy from mechanics to thermodynamics, emphasizing the role of heat. The first law, derived in the mid-1800s, highlights the crucial sign convention for work and heat. The lecture concludes by exploring the quantities regulated by the first law, including internal energy, work, and heat, with detailed examples and calculations.

Instructor

Ivo Furno

Teaching & PhD PhD Students Jules Amédée Aristobule Schadt, Renat Karimov, Amélie Renggli, Yuri Asnis, Michael Goddijn, Vanni Jonas Meier, Cyrille Sepulchre, Francesco D'Angelo Past EPFL PhD Students Federico Nespoli, Oulfa Chellai, Thibaut François Hugo Richard, Fabian Manke, Riccardo Agnello, Alexandra Waskow, Lorenzo Ibba, Agus Rita, Kadi Lyes Roland Past EPFL PhD Students as codirector Davoud Iraji, Christian Gabriel Theiler, Alexandre Dominique Bovet, Fabio Avino Courses General physics : thermodyn

Official source

Ontological neighbourhood

Physics

Thermodynamics: Statistical mechanics

Related concepts (25)

Thermodynamics

Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics.

Internal energy

The internal energy of a thermodynamic system is the energy contained within it, measured as the quantity of energy necessary to bring the system from its standard internal state to its present internal state of interest, accounting for the gains and losses of energy due to changes in its internal state, including such quantities as magnetization. It excludes the kinetic energy of motion of the system as a whole and the potential energy of position of the system as a whole, with respect to its surroundings and external force fields.

Laws of thermodynamics

The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships between them. They state empirical facts that form a basis of precluding the possibility of certain phenomena, such as perpetual motion.

Thermodynamic databases for pure substances

Thermodynamic databases contain information about thermodynamic properties for substances, the most important being enthalpy, entropy, and Gibbs free energy. Numerical values of these thermodynamic properties are collected as tables or are calculated from thermodynamic datafiles. Data is expressed as temperature-dependent values for one mole of substance at the standard pressure of 101.325 kPa (1 atm), or 100 kPa (1 bar). Both of these definitions for the standard condition for pressure are in use.

Chemical thermodynamics

Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the study of chemical questions and the spontaneity of processes. The structure of chemical thermodynamics is based on the first two laws of thermodynamics.

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