Activation energyIn chemistry and physics, activation energy is the minimum amount of energy that must be provided for compounds to result in a chemical reaction. The activation energy (Ea) of a reaction is measured in joules per mole (J/mol), kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol). Activation energy can be thought of as the magnitude of the potential barrier (sometimes called the energy barrier) separating minima of the potential energy surface pertaining to the initial and final thermodynamic state.
Gibbs free energyIn thermodynamics, the Gibbs free energy (or Gibbs energy as the recommended name; symbol ) is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure-volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure. It also provides a necessary condition for processes such as chemical reactions that may occur under these conditions. The Gibbs free energy is expressed as where p is pressure, T is the temperature, U is the internal energy, V is volume, H is the enthalpy, and S is the entropy.
Arrhenius equationIn physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates. The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and reverse reactions. This equation has a vast and important application in determining the rate of chemical reactions and for calculation of energy of activation.
Thermodynamic free energyIn thermodynamics, the thermodynamic free energy is one of the state functions of a thermodynamic system (the others being internal energy, enthalpy, entropy, etc.). The change in the free energy is the maximum amount of work that the system can perform in a process at constant temperature, and its sign indicates whether the process is thermodynamically favorable or forbidden. Since free energy usually contains potential energy, it is not absolute but depends on the choice of a zero point.
Helmholtz free energyIn thermodynamics, the Helmholtz free energy (or Helmholtz energy) is a thermodynamic potential that measures the useful work obtainable from a closed thermodynamic system at a constant temperature (isothermal). The change in the Helmholtz energy during a process is equal to the maximum amount of work that the system can perform in a thermodynamic process in which temperature is held constant. At constant temperature, the Helmholtz free energy is minimized at equilibrium.
MarsMars is the fourth planet and the furthest terrestrial planet from the Sun. The reddish color of its surface is due to finely grained iron(III) oxide dust in the soil, giving it the nickname "the Red Planet". Mars's radius is second smallest among the planets in the Solar System at . The Martian dichotomy is visible on the surface: on average, the terrain on Mars's northern hemisphere is flatter and lower than its southern hemisphere. Mars has a thin atmosphere made primarily of carbon dioxide and two irregularly shaped natural satellites: Phobos and Deimos.
Exploration of MarsThe planet Mars has been explored remotely by spacecraft. Probes sent from Earth, beginning in the late 20th century, have yielded a large increase in knowledge about the Martian system, focused primarily on understanding its geology and habitability potential. Engineering interplanetary journeys is complicated and the exploration of Mars has experienced a high failure rate, especially the early attempts. Roughly sixty percent of all spacecraft destined for Mars failed before completing their missions and some failed before their observations could begin.
Mars roverA Mars rover is a motor vehicle designed to travel on the surface of Mars. Rovers have several advantages over stationary landers: they examine more territory, they can be directed to interesting features, they can place themselves in sunny positions to weather winter months, and they can advance the knowledge of how to perform very remote robotic vehicle control. They serve a different purpose than orbital spacecraft like Mars Reconnaissance Orbiter. A more recent development is the Mars helicopter.
Timekeeping on MarsThough no standard exists, numerous calendars and other timekeeping approaches have been proposed for the planet Mars. The most commonly seen in the scientific literature denotes the time of year as the number of degrees on its orbit from the northward equinox, and increasingly there is use of numbering the Martian years beginning at the equinox that occurred April 11, 1955. Mars has an axial tilt and a rotation period similar to those of Earth. Thus, it experiences seasons of spring, summer, autumn and winter much like Earth.
Terraforming of MarsThe terraforming of Mars or the terraformation of Mars is a hypothetical procedure that would consist of a planetary engineering project or concurrent projects, with the goal to transform Mars from a planet hostile to terrestrial life to one that can sustainably host humans and other lifeforms free of protection or mediation. The process would involve the modification of the planet's extant climate, atmosphere, and surface through a variety of resource-intensive initiatives, and the installation of a novel ecological system or systems.
Life on MarsThe possibility of life on Mars is a subject of interest in astrobiology due to the planet's proximity and similarities to Earth. To date, no proof of past or present life has been found on Mars. Cumulative evidence suggests that during the ancient Noachian time period, the surface environment of Mars had liquid water and may have been habitable for microorganisms, but habitable conditions do not necessarily indicate life.
EnergyIn physics, energy () is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of heat and light. Energy is a conserved quantity—the law of conservation of energy states that energy can be converted in form, but not created or destroyed. The unit of measurement for energy in the International System of Units (SI) is the joule (J).
Equivalence relationIn mathematics, an equivalence relation is a binary relation that is reflexive, symmetric and transitive. The equipollence relation between line segments in geometry is a common example of an equivalence relation. Each equivalence relation provides a partition of the underlying set into disjoint equivalence classes. Two elements of the given set are equivalent to each other if and only if they belong to the same equivalence class.
TemperatureTemperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied on various reference points and thermometric substances for definition. The most common scales are the Celsius scale with the unit symbol °C (formerly called centigrade), the Fahrenheit scale (°F), and the Kelvin scale (K), the latter being used predominantly for scientific purposes.
Equivalence classIn mathematics, when the elements of some set have a notion of equivalence (formalized as an equivalence relation), then one may naturally split the set into equivalence classes. These equivalence classes are constructed so that elements and belong to the same equivalence class if, and only if, they are equivalent. Formally, given a set and an equivalence relation on the of an element in denoted by is the set of elements which are equivalent to It may be proven, from the defining properties of equivalence relations, that the equivalence classes form a partition of This partition—the set of equivalence classes—is sometimes called the quotient set or the quotient space of by and is denoted by .
Mass–energy equivalenceIn physics, mass–energy equivalence is the relationship between mass and energy in a system's rest frame, where the two quantities differ only by a multiplicative constant and the units of measurement. The principle is described by the physicist Albert Einstein's formula: . In a reference frame where the system is moving, its relativistic energy and relativistic mass (instead of rest mass) obey the same formula. The formula defines the energy E of a particle in its rest frame as the product of mass (m) with the speed of light squared (c2).
Equivalence principleIn the theory of general relativity, the equivalence principle is the equivalence of gravitational and inertial mass, and Albert Einstein's observation that the gravitational "force" as experienced locally while standing on a massive body (such as the Earth) is the same as the pseudo-force experienced by an observer in a non-inertial (accelerated) frame of reference. History of gravitational theory Something like the equivalence principle emerged in the early 17th century, when Galileo expressed experimentally that the acceleration of a test mass due to gravitation is independent of the amount of mass being accelerated.
Unruh effectThe Unruh effect (also known as the Fulling–Davies–Unruh effect) is a kinematic prediction of quantum field theory that a uniformly accelerating observer will observe a thermal bath, like blackbody radiation, whereas an inertial observer would observe none. In other words, the background appears to be warm from an accelerating reference frame; in layperson's terms, an accelerating thermometer (like one being waved around) in empty space, removing any other contribution to its temperature, will record a non-zero temperature, just from its acceleration.
Thermodynamic temperatureThermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are now understood as manifestations of the kinetic energy of free motion of microscopic particles such as atoms, molecules, and electrons.
Zeroth law of thermodynamicsThe zeroth law of thermodynamics is one of the four principal laws of thermodynamics. It provides an independent definition of temperature without reference to entropy, which is defined in the second law. The law was established by Ralph H. Fowler in the 1930s, long after the first, second, and third laws had been widely recognized. The zeroth law states that if two thermodynamic systems are in thermal equilibrium with each other, and also separately in thermal equilibrium with a third system, then the three systems are in thermal equilibrium with each other.
