Lecture

Binary Systems: Solid Solutions

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In course

MSE-101(b): Materials:from chemistry to properties

Ce cours permet l'acquisition des notions essentielles relatives à la structure de la matière, aux équilibres et à la réactivité chimique en liaison avec les propriétés mécaniques, thermiques, électriques, magnétiques et optiques des matériaux. ...

Description

This lecture discusses binary systems, focusing on solid solutions and the phase diagrams of miscible systems. It covers the concept of degrees of freedom, the influence of temperature and pressure, and the phase equilibrium conditions. The instructor explains the solidification process, the phase diagram construction, and the rule for phase equilibrium in two-phase domains. The lecture also touches on the molar free enthalpy curves and the minimization of free enthalpy in solid and liquid phases.

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Instructors (4)

Michel Rappaz

After a PhD in solid state physics (1978) at the Ecole Polytechnique Fédérale de Lausanne (EPFL) and a post-doc at Oak Ridge National Laboratory, Michel Rappaz joined the Institute of Materials of EPFL in 1981. After two years in an engineering company, he came back to EPFL in 1984 where he was nominated Adjunct Professor in 1990 and Full Professor in 2003. He retired from EPFL in 2015 and is now Emeritus Professor and independent consultant for several industries and research centres. His main interests are in phase transformations and solidification, in particular the coupling of macroscopic aspects of heat and mass transfer with microscopic aspects of microstructure and defect formation. Among his diverse achievements, one can mention in particular the development of cellular automata for grain structure predictions and of granular models for hot tearing formation in castings, the coupling of Finite Element method with microscopic models of nucleation and growth, the application of the phase field method to the understanding of various microstructures, the discovery of quasicrystal mediated-nucleation in alloys, and many other studies both fundamental at the microstructure-defect level and more applied at the level of processes. Some of the software developments have been commercialized by a spin-off company founded by his group in 1991 (Calcom SA), now part of the French company ESI. Michel Rappaz initiated in 1992 an annual postgraduate course on solidification which has been attended by more than 900 participants from all over the world. He is presently collaborating closely with another spin-off company started from his group, Novamet SàrL. Michel Rappaz has received several awards, in particular the Mathewson co-author award (1994) and author award (1997) of the American Mineral, Metals and Materials Society (TMS), the Koerber foundation award jointly with Profs Y. Bréchet and M. Asbby (1996), the Sainte-Claire Deville Medal (1996) and the Grand Medal (2011) from the French Materials Society, the Bruce Chalmers Award of TMS (2002), the Mc Donald Memorial Lecture award of Canada (2005), the FEMS European Materials Gold Medal (2013) and the Brimacombe Prize of TMS (2015). He is a highly-cited author of ISI, a fellow of ASM, IOP and TMS, and has co-authored more than 200 publications and two books.

Arianna Marchioro

Education PhD Thesis | Interfacial Charge Transfer Dynamics in Solid-State Hybrid Organic-Inorganic Solar Cells 2010 – 2014 EPFL Directed by Prof. J.-E. Moser and Prof. M. Grätzel MSc in Molecular and Biological Chemistry | 2008 – 2010 EPFL and Imperial College London (exchange program) BSc in Chemistry | 2005 – 2008 EPFL Professionals experiences Postdoctoral Research Associate 2014–2016 University of Washington, Seatt

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Related concepts (32)

Phase (matter)

In the physical sciences, a phase is a region of material that is chemically uniform, physically distinct, and (often) mechanically separable. In a system consisting of ice and water in a glass jar, the ice cubes are one phase, the water is a second phase, and the humid air is a third phase over the ice and water. The glass of the jar is another separate phase. (See .) More precisely, a phase is a region of space (a thermodynamic system), throughout which all physical properties of a material are essentially uniform.

Enthalpy of fusion

In thermodynamics, the enthalpy of fusion of a substance, also known as (latent) heat of fusion, is the change in its enthalpy resulting from providing energy, typically heat, to a specific quantity of the substance to change its state from a solid to a liquid, at constant pressure. It is the amount of energy required to convert one mole of solid into liquid. For example, when melting 1 kg of ice (at 0 °C under a ), 333.55 kJ of energy is absorbed with no temperature change.

Binary system

A binary system is a system of two astronomical bodies which are close enough that their gravitational attraction causes them to orbit each other around a barycenter (also see animated examples). More restrictive definitions require that this common center of mass is not located within the interior of either object, in order to exclude the typical planet–satellite systems and planetary systems. The most common binary systems are binary stars and binary asteroid, but brown dwarfs, planets, neutron stars, black holes and galaxies can also form binaries.

Enthalpy

Enthalpy ˈɛnθəlpi, a property of a thermodynamic system, is the sum of the system's internal energy and the product of its pressure and volume. It is a state function used in many measurements in chemical, biological, and physical systems at a constant pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work required to establish the system's physical dimensions, i.e. to make room for it by displacing its surroundings.

Chemical equilibrium

In a chemical reaction, chemical equilibrium is the state in which both the reactants and products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the system. This state results when the forward reaction proceeds at the same rate as the reverse reaction. The reaction rates of the forward and backward reactions are generally not zero, but they are equal. Thus, there are no net changes in the concentrations of the reactants and products.

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Fabien Sorin

Sep 2002-Oct 2007 Ph.D., Department of Materials Science and Engineering, MIT, USA. Supervisor: Prof. Yoel Fink; Thesis: Multi-material, Multifunctional Fiber Devices. After graduating with an engineering degree and a Master of Science in Physics from the Ecole Polytechnique in Palaiseau, France, Prof. Sorin joined the department of Materials Science and Engineering at the Massachusetts Institute of Technology (MIT) in Cambridge, USA for his graduate studies. He worked as a research assistant in the Photonic Bandgap Fibers and Devices Group of Professor Yoel Fink and graduated with a PhD in 2008. His PhD thesis led to the development of a new class of fiber material and devices and he was a pioneer of the field of multi-material fibers. Mar 2008-Oct 2010 Postdoctoral Associate and Research Scientist, Research Laboratory of Electronics, MIT. He then joined the Research Laboratory of Electronics at MIT as a Postdoctoral Associate, and continued as a Research Scientist associate, where he conducted independent research in the emerging field of multi-material fibers and was involved and led a variety of projects in fundamental research as well as in collaborations with local start-ups. Apr 2011 Feb 2013 Research Engineer, Saint-Gobain Recherche, Aubervilliers, France. Surface du Verre et interface Group In 2011, prof. Sorin returned to Europe and joined the company Saint-Gobain in the Saint-Gobain Recherche center, its biggest research center located near Paris in France. As a research engineer, he developed a new research thrust investigating new photonic materials and nanostructures for the energy and building industries. In particular, he and colleagues developed innovative processing approaches to deploy photonic nanostructures for light management over large area substrates, for applications in energy harvesting and saving, and for building materials and windows. Mar 2013 Present Assistant Professor tenure-track, Ecole Polytechnique Fédérale de Lausanne (EPFL), Switzerland. Head of the Photonic materials and fibre devices laboratory (FIMAP) Since March 2013, he is in the department of Materials Science (IMX) at the Ecole Polytechnique Fédérale de Lausanne (EPFL) as an assistant professor tenure-track. He is starting a research group on photonic materials and fiber devices (FIMAP), continuing on developing innovative materials processing approaches and photonic device architectures to develop new solutions in energy harvesting, saving and storage, in sensing and monitoring, health care and smart fabrics.

Related concepts (32)