Lecture

Carbonation and Microstructure

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Description

This lecture covers the study of carbonation and microstructure in cementitious materials, focusing on the effects of supplementary cementitious materials, relative humidity, temperature, and curing conditions. It explores the competition of mechanisms, the formation of different solid phases, and the impact of various factors on porosity and performance. The lecture also discusses the change in microstructure before and after carbonation, as well as the diffusion processes in different states. Techniques such as XRD, TGA, NMR, SEM-EDX, and MIP are combined to analyze carbonation depth, solid phases, pore solution, and mechanical properties.

In MOOC

Sorption and transport in cementitious materials

In the MOOC: “Cement chemistry and sustainable cementitious materials”; you learned how to create more sustainable cementitious materials. But concrete is not an inert rock. It is a dynamic porous material, which can exchange water, gas and ions with its environment. Through physical and chemical interactions, these exchanges can have dramatic consequences: cracks due to shrinkage, reinforcement bars corrosion, spalling, … For a true sustainability, the durability of cementitious materials should not be f

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Related concepts (32)

Solid-state chemistry

Solid-state chemistry, also sometimes referred as materials chemistry, is the study of the synthesis, structure, and properties of solid phase materials. It therefore has a strong overlap with solid-state physics, mineralogy, crystallography, ceramics, metallurgy, thermodynamics, materials science and electronics with a focus on the synthesis of novel materials and their characterization. A diverse range of synthetic techniques, such as the ceramic method and chemical vapour depostion, make solid-state materials.

Porosity

Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure the "accessible void", the total amount of void space accessible from the surface (cf. closed-cell foam). There are many ways to test porosity in a substance or part, such as industrial CT scanning.

Solid

Solid is one of the four fundamental states of matter (the others being liquid, gas, and plasma). The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structural rigidity (as in rigid bodies) and resistance to a force applied to the surface. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire available volume like a gas.

Phase (matter)

In the physical sciences, a phase is a region of material that is chemically uniform, physically distinct, and (often) mechanically separable. In a system consisting of ice and water in a glass jar, the ice cubes are one phase, the water is a second phase, and the humid air is a third phase over the ice and water. The glass of the jar is another separate phase. (See .) More precisely, a phase is a region of space (a thermodynamic system), throughout which all physical properties of a material are essentially uniform.

Amorphous solid

In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymously with amorphous solid; however, these terms refer specifically to amorphous materials that undergo a glass transition. Examples of amorphous solids include glasses, metallic glasses, and certain types of plastics and polymers. The term comes from the Greek a ("without"), and morphé ("shape, form").

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