Lecture

Optical Activity: Polarization Rotation & Chirality

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In course

PHYS-317: Optics I

L'optique est un vieux domaine qui touche à beaucoup de sujets modernes, des techniques expérimentales aux applications courantes. Ce premier cours traite plusieurs aspects de base de l'optique: propagation, dispersion, interférence, diffraction, polarisat ...

Description

This lecture covers the optical phenomena of circular birefringence, optical activity, and polarization rotation in materials like quartz and liquids. It explains the rotation of polarization by liquids, the difference between natural and synthetic chiral molecules, and the use of polarimeters to measure specific rotation coefficients. Additionally, it discusses the behavior of liquid crystals, Faraday and Kerr effects, Pockels effect in crystals, and the application of optical isolators. The lecture also explores the principle of separating light using chiral liquid interfaces and the application of polarization in CD/DVD play heads.

Instructor

Benjamin Dwir

Academic title: Dr. Birth date: 24.10.1959 Nationality: Swiss At EPFL since: 1988

Official source

Related concepts (20)

Chirality (chemistry)

In chemistry, a molecule or ion is called chiral (ˈkaɪrəl) if it cannot be superposed on its by any combination of rotations, translations, and some conformational changes. This geometric property is called chirality (kaɪˈrælɪti). The terms are derived from Ancient Greek χείρ (cheir) 'hand'; which is the canonical example of an object with this property. A chiral molecule or ion exists in two stereoisomers that are mirror images of each other, called enantiomers; they are often distinguished as either "right-handed" or "left-handed" by their absolute configuration or some other criterion.

Chirality

Chirality kaɪˈrælɪtiː is a property of asymmetry important in several branches of science. The word chirality is derived from the Greek χειρ (kheir), "hand", a familiar chiral object. An object or a system is chiral if it is distinguishable from its ; that is, it cannot be superimposed onto it. Conversely, a mirror image of an achiral object, such as a sphere, cannot be distinguished from the object. A chiral object and its mirror image are called enantiomorphs (Greek, "opposite forms") or, when referring to molecules, enantiomers.

Optical rotation

Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity. Optical activity occurs only in chiral materials, those lacking microscopic mirror symmetry. Unlike other sources of birefringence which alter a beam's state of polarization, optical activity can be observed in fluids.

Chiral media

The term chiral ˈkaɪrəl describes an object, especially a molecule, which has or produces a non-superposable mirror image of itself. In chemistry, such a molecule is called an enantiomer or is said to exhibit chirality or enantiomerism. The term "chiral" comes from the Greek word for the human hand, which itself exhibits such non-superimposeability of the left hand precisely over the right. Due to the opposition of the fingers and thumbs, no matter how the two hands are oriented, it is impossible for both hands to exactly coincide.

Faraday effect

The Faraday effect or Faraday rotation, sometimes referred to as the magneto-optic Faraday effect (MOFE), is a physical magneto-optical phenomenon. The Faraday effect causes a polarization rotation which is proportional to the projection of the magnetic field along the direction of the light propagation. Formally, it is a special case of gyroelectromagnetism obtained when the dielectric permittivity tensor is diagonal. This effect occurs in most optically transparent dielectric materials (including liquids) under the influence of magnetic fields.

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