Lecture

Chemical Equilibrium and Matter Transfer

Graph Chat

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

Description

This lecture covers the concepts of chemical equilibrium and matter transfer in two simple subsystems separated by a diathermic, immobile, and permeable wall. It discusses the laws of Fick, discrete and continuous formulations, and the thermodynamic principles governing the systems' energy and entropy. The lecture also explores the extensivity of entropy and the number of moles, partial derivatives of entropy, and the conditions for chemical equilibrium and irreversible processes in matter transfer.

In MOOC

Thermodynamics II

The aim of the course is to enable students to understand and apply the fundamental concepts of thermodynamics. After presenting the first and second principles of thermodynamics, the lecture will address questions of irreversibility and thermodynamic potentials. After establishing these conceptual foundations, which are the subject of the first part, their engineering applications, such as heat transfer, calorimetry and phase transitions, will be covered. Next, we'll look at the conversion of chemical en

Official source

Ontological neighbourhood

Physics

Thermodynamics: Statistical mechanics

Related concepts (32)

Non-equilibrium thermodynamics

Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities (non-equilibrium state variables) that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium. Non-equilibrium thermodynamics is concerned with transport processes and with the rates of chemical reactions.

Chemical thermodynamics

Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the study of chemical questions and the spontaneity of processes. The structure of chemical thermodynamics is based on the first two laws of thermodynamics.

Thermodynamics

Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics.

Irreversible process

In science, a process that is not reversible is called irreversible. This concept arises frequently in thermodynamics. All complex natural processes are irreversible, although a phase transition at the coexistence temperature (e.g. melting of ice cubes in water) is well approximated as reversible. In thermodynamics, a change in the thermodynamic state of a system and all of its surroundings cannot be precisely restored to its initial state by infinitesimal changes in some property of the system without expenditure of energy.

Laws of thermodynamics

The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships between them. They state empirical facts that form a basis of precluding the possibility of certain phenomena, such as perpetual motion.

Related lectures (64)

Thermodynamics in Cell Biology

Explores the role of thermodynamics in cell biology, focusing on the connection between thermodynamics and cellular processes.

Thermodynamic Equilibrium and Mechanical Transfer MOOC: Thermodynamics II

Explores mechanical equilibrium, entropy, and irreversible processes in thermodynamics.

Entropy: Heat and Processes

Explores entropy, heat transfer, friction, and mechanical power conversion in various systems.

Thermodynamics: Exploring Thermodynamic Potentials and Equilibrium States

Covers thermodynamic potentials and their role in system equilibrium with reservoirs.

Second Law of Thermodynamics: Motivations