Mediaspace scheduled maintenance: Aug 25, 2026 07:00 - 12:00 AM. During this time, videos will be temporarily unavailable. Check status updates.

Lecture

Thermodynamics: Enthalpy and Standard Reactions

In course

MSE-101(a): Materials:from chemistry to properties

Ce cours permet l'acquisition des notions essentielles relatives à la structure de la matière, aux équilibres et à la réactivité chimique en liaison avec les propriétés mécaniques, thermiques, électriques et magnétiques des matériaux. ...

Description

This lecture introduces the concept of enthalpy and standard reactions in thermodynamics, covering topics such as enthalpy of reaction, enthalpy of formation, and enthalpy of fusion. The lecture also discusses the principles of equilibrium, heat exchange, and energy conservation in chemical reactions.

Instructor

Véronique Michaud

Background: 1994 Habilitation à diriger des recherches ( INPG, France) 1991 PhD in Materials Engineering ( MIT, USA) 1987 Ingénieur Civil des Mines ( Ecole des Mines de Paris, France) Activities: Since January 2018: Associate Dean of Engineering, in charge of Education June 2012-Dec.2017: Head of the Materials Science and Engineering Section Since April 2017: Associate Professor at EPFL 2009-2017 : Professeur Titulaire at EPFL 1997-2009: Researcher at EPFL 1994-1997 : Chef de Travaux au laboratoire MSS-MAT, Ecole Centrale Paris (France) 1991-1994 : Post-doctoral research associate, MIT (USA) Author of about 300 publications of which 140 in peer-reviewed journals

Official source

Ontological neighbourhood

Physics

Thermodynamics: Statistical mechanics

Related concepts (32)

Standard enthalpy of reaction

The standard enthalpy of reaction (denoted ) for a chemical reaction is the difference between total reactant and total product molar enthalpies, calculated for substances in their standard states. This can in turn be used to predict the total chemical bond energy liberated or bound during reaction, as long as the enthalpy of mixing is also accounted for. For a generic chemical reaction the standard enthalpy of reaction is related to the standard enthalpy of formation values of the reactants and products by the following equation: In this equation, and are the stoichiometric coefficients of each product and reactant.

Enthalpy

Enthalpy ˈɛnθəlpi, a property of a thermodynamic system, is the sum of the system's internal energy and the product of its pressure and volume. It is a state function used in many measurements in chemical, biological, and physical systems at a constant pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work required to establish the system's physical dimensions, i.e. to make room for it by displacing its surroundings.

Standard enthalpy of formation

In chemistry and thermodynamics, the standard enthalpy of formation or standard heat of formation of a compound is the change of enthalpy during the formation of 1 mole of the substance from its constituent elements in their reference state, with all substances in their standard states. The standard pressure value p^⦵ = 10^5 Pa (= 100 kPa = 1 bar) is recommended by IUPAC, although prior to 1982 the value 1.00 atm (101.325 kPa) was used. There is no standard temperature. Its symbol is Δ_fH^⦵.

IPad

The iPad is a brand of iOS and iPadOS-based tablet computers that are developed by Apple Inc, first introduced on January 27, 2010. The iPad range consists of the original iPad lineup and the flagship products iPad Mini, iPad Air, and iPad Pro. The iPhone's iOS operating system (OS) was initially used for the iPad but in September 2019, its OS was switched to a fork of iOS called iPadOS that has better support for the device's hardware and its user interface is customized for the tablets' larger screens.

Thermodynamics

Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics.

Related lectures (45)

Thermodynamics: Energy Transformation

Covers energy transformation in thermodynamics, discussing laws, entropy, and spontaneity criteria for reactions.

Thermodynamics: Principles and Chemical Equilibrium

Explores thermodynamics principles, enthalpy of reactions, and chemical equilibrium with practical examples.

Chemical Thermodynamics: Fundamentals and Applications

Covers the basics of chemical thermodynamics, including enthalpy, phase changes, and calculation methods.

Chemistry: Atomic Structure and Thermodynamics

Covers atomic structure, thermodynamics, material properties, and ideal gas law.

Physical Meaning of Potentials (conclusion)