Lecture

Liquids in Nanochannels: Size Effects

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In course

ME-469: Nano-scale heat transfer

In this course we study heat transfer (and energy conversion) from a microscopic perspective. First we focus on understanding why classical laws (i.e. Fourier Law) are what they are and what are their limits of validity. Next we discuss emerging opportunit ...

Description

This lecture explores the size effects on liquids in nanochannels, covering topics such as interfacial interactions, electric double layer potential, phase transitions, surface tension, and electrophoresis of charged particles and ions. The instructor discusses the impact of curvature on vapor pressure, equilibrium phase transition temperature, and the validity of Navier-Stokes equations in nanochannels.

Instructor

Giulia Tagliabue

Dr. Giulia Tagliabue is an Assistant Professor at the Institute of Mechanical Engineering (IGM). She obtained her B.S. and M.S degrees cum laude in Mechanical Engineering from the University of Udine in Italy. Concurrently she also obtained the diploma from the Scuola Normale Superiore of Udine. In 2015 she obtained her PhD in Mechanical Engineering from ETH Zurich with a thesis on nanophotonic design for light-to-heat and light-to-charge conversion devices. In 2015 Dr. Tagliabue was awarded the Early Mobility Fellowship from the Swiss National Science Foundation and moved to Caltech as a PostDoctoral fellow. In 2017, thanks to the award of an Advanced Mobility Fellowship, she prolonged her stay at Caltech. Here, in collaboration with the Joint Center for Artificial Photosynthesis (JCAP) she investigated coupled light, heat and charge transfer processes in nanophotonic structures and low-dimensional materials for photoelectrochemical and photovoltaic sustainable energy conversion.

Official source

Related concepts (32)

Double layer (surface science)

In surface science, a double layer (DL, also called an electrical double layer, EDL) is a structure that appears on the surface of an object when it is exposed to a fluid. The object might be a solid particle, a gas bubble, a liquid droplet, or a porous body. The DL refers to two parallel layers of charge surrounding the object. The first layer, the surface charge (either positive or negative), consists of ions which are adsorbed onto the object due to chemical interactions.

Gel electrophoresis

Gel electrophoresis is a method for separation and analysis of biomacromolecules (DNA, RNA, proteins, etc.) and their fragments, based on their size and charge. It is used in clinical chemistry to separate proteins by charge or size (IEF agarose, essentially size independent) and in biochemistry and molecular biology to separate a mixed population of DNA and RNA fragments by length, to estimate the size of DNA and RNA fragments or to separate proteins by charge.

Liquid

A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a nearly constant volume independent of pressure. It is one of the four fundamental states of matter (the others being solid, gas, and plasma), and is the only state with a definite volume but no fixed shape. The density of a liquid is usually close to that of a solid, and much higher than that of a gas. Therefore, liquid and solid are both termed condensed matter.

Electrophoresis

Electrophoresis is the motion of dispersed particles relative to a fluid under the influence of a spatially uniform electric field. Electrophoresis of positively charged particles (cations) is sometimes called cataphoresis, while electrophoresis of negatively charged particles (anions) is sometimes called anaphoresis. The electrokinetic phenomenon of electrophoresis was observed for the first time in 1807 by Russian professors Peter Ivanovich Strakhov and Ferdinand Frederic Reuss at Moscow University, who noticed that the application of a constant electric field caused clay particles dispersed in water to migrate.

Agarose gel electrophoresis

Agarose gel electrophoresis is a method of gel electrophoresis used in biochemistry, molecular biology, genetics, and clinical chemistry to separate a mixed population of macromolecules such as DNA or proteins in a matrix of agarose, one of the two main components of agar. The proteins may be separated by charge and/or size (isoelectric focusing agarose electrophoresis is essentially size independent), and the DNA and RNA fragments by length.

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