Lecture

Chemical Reaction Engineering

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In course

ChE-340: The engineering of chemical reactions

Ce cours applique les concepts de la cinétique chimique et des bilans de masse et d'énergie pour résoudre les problèmes de génie des réactions chimiques, en mettant l'accent sur les applications industrielles. Les étudiants développent leur capacité d'anal ...

Description

This lecture covers problem-solving algorithms in chemical reaction engineering, including mole balance equations, rate laws, stoichiometry, and reactor design equations. It discusses the determination of reaction rates, equilibrium constants, and the impact of temperature on reactions. The lecture also explores elementary and non-elementary rate laws, power law models, and heterogeneous rate laws.

Instructors (3)

Albert Renken

Teaching & PhD Past EPFL PhD Students Serge Maeder, Jacques Membrez, Stéphane Porchet, Philippe Menoud, Brigitta Frank, Harvey Randall, Wolfgang Zimmerer, Frédéric Van Vyve, Serge Golay, Jianzhong Yang, Stéphane Dubuis, Philippe Warnery, Anders Nattorp, Christian Spühler, Laurent Cavin, Miriam Lorenzi, Bastien Monnerat, André Rouge, Olivier Wolfrath, Peter Stahl, Ralf Maurer, Konrad Geissler, Volker Höller, Benoît Louis, Pierre Reuse, Fabio Rainone, Eric Joannet, Chrystèle Horny Past EPFL PhD Students as co

Thierry Chappuis

Ardemis Anoush Boghossian

Official source

Related concepts (32)

Rate equation

In chemistry, the rate law or rate equation for a chemical reaction is a mathematical equation that links the rate of forward reaction with the concentrations or pressures of the reactants and constant parameters (normally rate coefficients and partial reaction orders). For many reactions, the initial rate is given by a power law such as where [\mathrm{A}] and [\mathrm{B}] express the concentration of the species \mathrm{A} and \mathrm{B}, usually in moles per liter (molarity, M).

Reaction rate constant

In chemical kinetics, a reaction rate constant or reaction rate coefficient (k) is a proportionality constant which quantifies the rate and direction of a chemical reaction by relating it with the concentration of reactants. For a reaction between reactants A and B to form a product C, where A and B are reactants C is a product a, b, and c are stoichiometric coefficients, the reaction rate is often found to have the form: Here k is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the solution.

Rate-determining step

In chemical kinetics, the overall rate of a reaction is often approximately determined by the slowest step, known as the rate-determining step (RDS or RD-step or r/d step) or rate-limiting step. For a given reaction mechanism, the prediction of the corresponding rate equation (for comparison with the experimental rate law) is often simplified by using this approximation of the rate-determining step. In principle, the time evolution of the reactant and product concentrations can be determined from the set of simultaneous rate equations for the individual steps of the mechanism, one for each step.

Chemical reaction

A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur.

Nuclear reactor

A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat from nuclear fission is passed to a working fluid (water or gas), which in turn runs through steam turbines. These either drive a ship's propellers or turn electrical generators' shafts. Nuclear generated steam in principle can be used for industrial process heat or for district heating.

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