Lecture

Thermodynamics Basics

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In course

ME-251: Thermodynamics and energetics I

The course introduces the basic concepts of thermodynamics and heat transfer, and thermodynamic properties of matter and their calculation. The students will master the concepts of heat, mass, and momentum conservation, and apply these concepts to thermody ...

Description

This lecture covers the fundamental concepts of thermodynamics, including the laws governing energy conservation and thermodynamic equilibrium. It explains the definitions of system, boundary, and surrounding, as well as state functions and different types of thermodynamic systems. The lecture also delves into the thermodynamic state of a system, characterizing it through properties like volume, pressure, temperature, and internal energy. Various forms of work, such as expansion, compression, and electrical work, are discussed, along with the different types of energy, including kinetic, potential, and internal energy. The presentation concludes with a review of energy concepts in mechanics and the application of energy conservation to closed systems.

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Instructors (2)

Daniel Favrat

Daniel Favrat got his Master degree in Mechanical Engineering from EPFL in 1972 and his PhD also from EPFL. He then spent 12 years in industrial research laboratories in Canada (Esso Canada) and Switzerland (CERAC: Centre Européen de Recherche Atlas Copco). From 1988 to 2013, he was full professor and director of the Industrial Energy Systems Laboratory (LENI) at EPFL. During that period he was successively director of the Institute of Energy and director of the Institute of Mechanical Engineering. From August 2013 he works at EPFL Energy Center first as director ad interim and now as director technologies. His research fields include systemic analyses accounting for energy, environment and economics (so-called environomic optimisation) and advanced conversion systems for a more rational use of energy (heat pumps &ORC, engines, fuel cells, power plants, etc). He is a member of the Swiss Academy of Engineering Sciences and of the National Academy of Technology in France. He has also an active participation in the World Federation of Engineering Organizations (WFEO) as a member of the executive committee and vice-chair of the energy committee. He is associate editor of the journal "Energy" and of International Journal of thermodynamics. He is the author of several books on thermodynamics and energy systems analysis. He is also affiliate professor at the Royal Institute of Technology (KTH) in Stockholm.

Sophia Haussener

Sophia Haussener is an Associate Professor heading the Laboratory of Renewable Energy Science and Engineering at the Ecole Polytechnique Fédérale de Lausanne (EPFL). Her current research is focused on providing design guidelines for thermal, thermochemical, and photoelectrochemical energy conversion reactors through multi-physics modeling. Her research interests include: thermal sciences, fluid dynamics, charge transfer, electro-magnetism, and thermo/electro/photochemistry in complex multi-phase media on multiple scales. She received her MSc (2007) and PhD (2010) in Mechanical Engineering from ETH Zurich. Between 2011 and 2012, she was a postdoctoral researcher at the Joint Center of Artificial Photosynthesis (JCAP) and the Energy Environmental Technology Division of the Lawrence Berkeley National Laboratory (LBNL). She has published over 70 articles in peer-reviewed journals and conference proceedings. She has been awarded the ETH medal (2011), the Dimitris N. Chorafas Foundation award (2011), the ABB Forschungspreis (2012), the Prix Zonta (2015), the Global Change Award (2017), and the Raymond Viskanta Award (2019), and is a recipient of a Starting Grant of the Swiss National Science Foundation (2014). She is a deputy leader in the Swiss Competence Center for Energy Research (SCCER) on energy storage and acts as a Member of the Scientific Advisory Council of the Helmholtz Zentrum.

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Related concepts (32)

Thermodynamic equilibrium

Thermodynamic equilibrium is an axiomatic concept of thermodynamics. It is an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable walls. In thermodynamic equilibrium, there are no net macroscopic flows of matter nor of energy within a system or between systems. In a system that is in its own state of internal thermodynamic equilibrium, no macroscopic change occurs.

Thermodynamic process

Classical thermodynamics considers three main kinds of thermodynamic process: (1) changes in a system, (2) cycles in a system, and (3) flow processes. (1)A Thermodynamic process is a process in which the thermodynamic state of a system is changed. A change in a system is defined by a passage from an initial to a final state of thermodynamic equilibrium. In classical thermodynamics, the actual course of the process is not the primary concern, and often is ignored.

Heat

In thermodynamics, heat is the thermal energy transferred between systems due to a temperature difference. In colloquial use, heat sometimes refers to thermal energy itself. An example of formal vs. informal usage may be obtained from the right-hand photo, in which the metal bar is "conducting heat" from its hot end to its cold end, but if the metal bar is considered a thermodynamic system, then the energy flowing within the metal bar is called internal energy, not heat.

Thermodynamic equations

Thermodynamics is expressed by a mathematical framework of thermodynamic equations which relate various thermodynamic quantities and physical properties measured in a laboratory or production process. Thermodynamics is based on a fundamental set of postulates, that became the laws of thermodynamics. One of the fundamental thermodynamic equations is the description of thermodynamic work in analogy to mechanical work, or weight lifted through an elevation against gravity, as defined in 1824 by French physicist Sadi Carnot.

Non-equilibrium thermodynamics

Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities (non-equilibrium state variables) that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium. Non-equilibrium thermodynamics is concerned with transport processes and with the rates of chemical reactions.

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