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Concept

Tafel equation

Related publications (28)

VHDL-AMS Model of an Electrochemical Cell to Design VLSI Bio-Chips

Giovanni De Micheli, Yusuf Leblebici, Sandro Carrara, Alain Vachoux

This paper presents a new VHDL-AMS behavioral model of an electrochemical cell suitable for the design of VLSI bio-chips. Existing models are mainly equivalent circuit macromodels using electrical primitives, which hardly fit the actual behavior of biosens ...

2011

Evolution of an Oxygen Near-Edge X-ray Absorption Fine Structure Transition in the Upper Hubbard Band in alpha-Fe2O3 upon Electrochemical Oxidation

Michael Graetzel, Kevin Sivula

Electrochemical oxidation of hematite (alpha-Fe2O3) nanoparticulate films at 600 mV vs Ag+/AgCl in KOH electrolyte forms a species at the hematite surface which causes a new transition in the upper Hubbard band between the Fe(3d)-O(2p) state region and the ...

American Chemical Society2011

Investigation of the Pt/YSZ interface at low oxygen partial pressure by solid electrochemical mass spectroscopy under high vacuum conditions

Christos Comninellis, György Foti, Wolfgang Harbich, Cyril Falgairette, Chun Xia

The Pt/YSZ interface was investigated at low oxygen partial pressure under high vacuum (HV) conditions at 400 A degrees C. Two different electrochemical techniques were coupled to mass spectrometric gas analysis using a new solid electrochemical mass spect ...

Springer Netherlands2010

Solid electrochemical mass spectrometry (SEMS) for investigation of supported metal catalysts under high vacuum

Christos Comninellis, Wolfgang Harbich, Cyril Falgairette, Chun Xia

A new experimental set-up, coupling electrochemistry and mass spectroscopic techniques, for the investigation of a solid electrochemical cell under high vacuum conditions (HV) is presented. Two configurations are realized allowing the investigation of both ...

Springer Netherlands2010

Electrochemical Investigation of the O-2(g),Ni/YSZ System Using Cyclic Voltammetry

Christos Comninellis, Cyril Falgairette

Cyclic voltammetry was used for the electrochemical study of a Ni thin film (similar to 880 nm) deposited on an yttria-stabilized zirconia (YSZ) solid electrolyte pellet at temperatures between 350 and 450 degrees C at 20 kPa O-2 and atmospheric pressure. ...

2010

Stored Electrogenerated Promoters Inducing Sustainable Enhanced Pt Catalyst Activity

Cyril Falgairette

This work concerns the investigation of the electrochemical promotion of Pt/YSZ catalyst giving more emphasis to the sustainable enhanced catalytic activity after current interruption. The permanent electrochemical promotion (P-EPOC) of C2H4 combustion ove ...

EPFL2010

Electrocatalysis induced by surface redox activities on conductive metal oxide electrodes

Stéphane Fierro

Iridium dioxide electrodes form part of the dimensionally stable anodes (DSA®) and this electrode material is widely used in many industrial processes namely water electrolysis, metal electro-winning, cathodic protection and electro-organic synthesis due t ...

EPFL2010

Electrochemical comparison between IrO2 prepared by anodic oxidation of pure iridium and IrO2 prepared by thermal decomposition of H2IrC16 precursor solution

Christos Comninellis, Stéphane Fierro

Surface redox activities, oxygen evolution reaction (OER), oxidation of formic acid (FA), and anodic stability were investigated and compared for IrO2 electrodes prepared by two techniques: the thermal decomposition of H2IrCl6 precursor (TDIROF) and the an ...

Springer Netherlands2009