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Concept

Hydrosilylation

Related publications (22)

Embedding an Allylmetal Dimer in a Chiral Cavity: The Unprecedented Stereoselectivity of a Twofold Wittig [1,2]-Rearrangement

Frédéric Bailly

After alpha,alpha'-dimetalation, both 2,2'-diallyloxy-1,1'-binaphthyl and 2,2'-di-2-methylallyloxy-1,1'-binaphthyl undergo the Wittig rearrangement with perfect diastereoselectivity. When racemic 1,1'-binaphthyl-2,2'-diol ("BINOL") is used as the starting ...

2006

Cooperative effect between iridium and platinum in the carbonylation of methanol to acetic acid

Gabor Laurenczy

The iodocarbonyl monomer [PtI2(CO)2] 7 promotes the iridium catalyzed carbonylation of methanol to acetic acid at low water contents. Studies based on low pressure or high pressure NMR and the use of labeled reactants were cond ...

2006