Concept

Endmember

An endmember (also end-member or end member) in mineralogy is a mineral that is at the extreme end of a mineral series in terms of purity of its chemical composition. Minerals often can be described as solid solutions with varying compositions of some chemical elements, rather than as substances with an exact chemical formula. There may be two or more endmembers in a group or series of minerals. For example, forsterite (Mg2SiO4) and fayalite (Fe2SiO4) are the two end-members of the olivine solid-solution series, varying in Mg2+ and Fe2+ in their chemical composition. So, the chemical formula of olivine can be better expressed as or . As another example, the tectosilicate feldspar can be described as a solid solution of the endmembers K-feldspar (KAlSi3O8), albite (NaAlSi3O8) and anorthite (CaAl2Si2O8). A specific feldspar can have varying quantities of potassium (K), sodium (Na) and calcium (Ca).

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https://en.wikipedia.org/wiki/Endmember

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Related people (2)

Nicola Marzari

Dragan Damjanovic

Dragan Damjanovic received BSc diploma in Physics from the Faculty of Natural Sciences and Mathematics, University of Sarajevo, in 1980, and PhD in Ceramics Science from the Department of Materials Science and Engineering, College of Earth and Mineral Sciences, the Pennsylvania State University (PSU) in 1987. From 1988 to 1991 he was a research associate in the Materials Research Laboratory at the PSU. He joined the Ceramics Laboratory, Department of Materials Science and Engineering, Ecole polytechnique fédérale de Lausanne in 1991. He is currently a "professeur titulaire", heads the Group for Ferroelectrics and Functional Oxides at the Institute of Materials and teaches undergraduate and graduate courses on structure and electrical properties of materials. The research activities include fundamental and applied investigations of piezoelectric, ferroelectric and dielectric properties of a broad class of materials.

Related concepts (3)

Fayalite

Fayalite (Fe2SiO4, commonly abbreviated to Fa) is the iron-rich end-member of the olivine solid-solution series. In common with all minerals in the olivine group, fayalite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a 4.82 Å, b 10.48 Å and c 6.09 Å. Fayalite forms solid solution series with the magnesium olivine endmember forsterite (Mg2SiO4) and also with the manganese rich olivine endmember tephroite (Mn2SiO4).

Solid solution

A solid solution, a term popularly used for metals, is a homogeneous mixture of two different kinds of atoms in solid state and having a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solution" is used to describe the intimate mixing of components at the atomic level and distinguishes these homogeneous materials from physical mixtures of components. Two terms are mainly associated with solid solutions – solvents and solutes, depending on the relative abundance of the atomic species.

Forsterite

Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a 4.75 Å (0.475 nm), b 10.20 Å (1.020 nm) and c 5.98 Å (0.598 nm). Forsterite is associated with igneous and metamorphic rocks and has also been found in meteorites. In 2005 it was also found in cometary dust returned by the Stardust probe.

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