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Concept

Adduct

Related publications (24)

ESI-MS characterisation of protein adducts of anticancer ruthenium(II)-arene PTA (RAPTA) complexes

Paul Joseph Dyson, Wee Han Ang, Angela Casini

Electrospray ionization mass spectrometry allows a rapid characterization of the adducts formed between three novel anticancer ruthenium(II)-arene PTA compds. and horse heart cytochrome c or hen egg white lysozyme. Specific information on the nature of the ...

2007

Silver Complexes of Cyclic Hexachlorotriphosphazene

The first solid-state structures of complexed P3N3X6 (X=halogen) are reported for X=Cl. The compounds were obtained from P3N3Cl6 and Ag[Al(OR)4] salts in CH2Cl2/CS2 solution. The very weakly coordinating anion with R=C(CF3)3 led to the salt Ag(P3N3Cl6)2+[A ...

2006

Studies on the synthesis, structure and reactivity of heterocyclic metallonitridophosphinates

T-BuP(NH2)2 reacts with base-stabilized group 13 tri-hydrides with adduct formation (THF-BH3), with redn. to give t-BuPH2 (Me3N-AlH3) and with elimination of H22 and formation of a metallonitridophosphinate (Me3N-GaH3). In contrast, the reaction with Cp*Ti ...

2005

Meta- rather than ortho-directed metalations: Buttressing effects prejudicing the proton abstraction from (2,6-dihalophenyl)silanes

Fabrice Cottet, Christophe Heiss

(2,6-Dichlorophenyl)trimethyl- and -triethylsilane exhibit untypical reactivity patterns toward strong bases. When treated at -100 DegC with lithium 2,2,6,6-tetramethylpiperidide, they give rise to two, with sec- or tert-butyllithium even three, different ...

2005