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Concept

Hydrogen cyanide

Related publications (13)

Operando diffuse reflectance infrared detection of cyanide intermediate species during the reaction of formaldehyde with ammonia over V2O(5)/ WO3-TiO2

Oliver Kröcher, Davide Ferri, Rob Jeremiah G. Nuguid

Hydrogen cyanide (HCN) is a highly poisonous gas that can form through the reaction between formaldehyde and ammonia (NH3) in the exhaust. While this detrimental side reaction has been the subject of recent catalytic studies under selective catalytic reduc ...

ELSEVIER2021

HCN production from formaldehyde during the selective catalytic reduction of NOx with NH3 over V2O5/WO3-TiO2

Oliver Kröcher, Davide Ferri, Rob Jeremiah G. Nuguid

Raw exhaust gases may contain notable levels of formaldehyde that can negatively impact the efficiency of after -treatment systems. In the selective catalytic reduction (SCR) of NOx over V2O5/WO3-TiO2, formaldehyde was found to react with NH3 to produce HC ...

ELSEVIER2021

A smart low molecular weight gelator for the triple detection of copper (II), mercury (II), and cyanide ions in water resources

Rosario Scopelliti

Novel supramolecular gelators based on quinoline-indolin-2-one structure were synthesized. These gelators formed stable organogels in a mixture of DMSO/H2O (1:1). The scanning electron microscopy (SEM), IR and NMR spectroscopies, and rheological measuremen ...

ELSEVIER2020

Copper-Catalyzed Cyanoalkylative Aziridination of N-Sulfonyl Allylamines

Jieping Zhu, Qian Wang, Minh Tu Ha, Weisi Guo

Reaction of N-arylsulfonyl allylamines with alkyl nitriles in the presence of di-tert-butyl peroxide (DTBP) and a catalytic amount of copper salt afforded homologated aziridines in 43-86% yield. A sequence involving addition of the in situ generated cyanom ...

Wiley2020

Fiber-Tip Polymer Microcantilever for Fast and Highly Sensitive Hydrogen Measurement

Giovanni Dietler, Sandor Kasas, Jiangtao Zhou, Leonardo Venturelli

Hydrogen as an antioxidant gas has been widely used in the medical and biological fields for preventing cancer or treating inflammation. However, controlling the hydrogen concentration is crucial for practical use due to its explosive property when its vol ...

AMER CHEMICAL SOC2020

Gas-Phase Ozone Reactions with a Structurally Diverse Set of Molecules: Barrier Heights and Reaction Energies Evaluated by Coupled Cluster and Density Functional Theory Calculations

Jeremy Samuel Arey, Peter Rudolf Tentscher, Daniela Trogolo

Reactions with ozone transform organic and inorganic molecules in water treatment systems as well as in atmospheric chemistry, either in the aqueous phase, at gas/particle interfaces, or in the gas phase. Computed thermokinetic data can be used to estimate ...

AMER CHEMICAL SOC2019

Metal hydride compressor control device and method

Andreas Züttel, Noris André Gallandat

The present relates to a Metal hydride compressor control method for generating a variable output pressure P_desired_outPut, comprising a first step of inflowing gaseous hydrogen into a metal hydride compartment at a constant temperature and then stopping ...

2019

Crossed Molecular Beams and Theoretical Studies of the O(P-3)+1,2-Butadiene Reaction: Dominant Formation of Propene plus CO and Ethylidene plus Ketene Molecular Channels

Silvia Tanteri, Adriana Caracciolo

Detailed understanding of the mechanism of the combustion relevant multichannel reactions of O(P-3) with unsaturated hydrocarbons (UHs) requires the identification of all primary reaction products, the determination of their branching ratios and assessment ...

CHINESE PHYSICAL SOC2019

Photochemistry of 1- and 2-Naphthols and their Water Clusters: The Role of 1ππ*(La) Mediated Hydrogen Transfer to Carbon Atoms

Anne-Clémence Corminboeuf, Antonio Prlj

The computational analysis of isomer- and conformer- dependent photochemistry of 1- and 2-naphthols and their microsolvated water clusters is motivated by their very different excited state reactivity. We present evidence that 1- and 2-naphthol follow dist ...

Wiley-V C H Verlag Gmbh2017

Effect of Very High Charge Density and Monomer Constitution on the Synthesis and Properties of Cationic Polyelectrolytes

Jutta Christine Wandrey, Hamideh Ahmadloo

The free-radical homopolymerization of 1,3-bis(N,N,N-trimethylammonium)-2-propylmethacrylate dichloride (di-M) and 1,3-bis(N,N,N-trimethylammonium)-2-propylacrylate dichloride (di-A) in aqueous solution yields cationic polyelectrolytes (PEL) with theoretic ...

Mdpi Ag2016

Synthesis and Reactivity of Mononuclear Iron Models of [Fe]-Hydrogenase that Contain an Acylmethylpyridinol Ligand

Xile Hu, Dafa Chen

[Fe]-hydrogenase has a single iron-containing active site that features an acylmethylpyridinol ligand. This unique ligand environment had yet to be reproduced in synthetic models; however the synthesis and reactivity of a new class of small molecule mimics ...

Wiley-V C H Verlag Gmbh2014

A bright tetranuclear iridium(III) complex

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti, Davide Di Censo

A cyclic tetranuclear cyclometallated iridium(III) complex using cyanide anions as bridging ligands and displaying a tetrahedrally distorted square geometry has been obtained with high yield; photo- and electrochemical characterizations show that most inte ...

Royal Society of Chemistry2011

Characterization of perovskite powders for cathode and oxygen membranes made by different synthesis routes

Philippe Buffat, Jan Van Herle, Elena Suvorova Buffat, Nicolas Xanthopoulos

Strontium lanthanum manganite (LSM) and lanthanum ferrite (LSF) perovskite cathode and oxygen membrane materials were synthesized using different techniques: spray pyrolysis, a modified citrate route, oxalate and carbonate co-precipitations. The use of Ca, ...

2005