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Concept

Polycyclic compound

Related publications (25)

A Rhodium Nanoparticle-Lewis Acidic Ionic Liquid Catalyst for the Chemoselective Reduction of Heteroarenes

Paul Joseph Dyson, Shoubhik Das, Aswin Gopakumar, Alena Karakulina, Ismail Akçok

We describe a catalytic system composed of rhodium nanoparticles immobilized in a Lewis acidic ionic liquid. The combined system catalyzes the hydrogenation of quinolines, pyridines, benzofurans, and furan to access the corresponding heterocycles, importan ...

Wiley-VCH Verlag GmbH2016

Reaction between propargyl radical and 1,3-butadiene to form five to seven membered rings. Theoretical study

Daniela Trogolo

Propargyl radical addition to 1,3-butadiene seems to be a promising channel to form 5-, 6-, and 7-membered rings. These are important steps in the growth of polycyclic aromatic hydrocarbons and soot platelets. The reaction mechanism, involving 97 intermedi ...

Elsevier Science Inc2016

Nanoparticle - Ionic Liquid Based Catalytic Systems

Alena Karakulina

In recent years ionic liquids have emerged as an important class of compounds for the synthesis of metal nanoparticles. The significant advantage of using ionic liquids is their dual role of reaction solvent and nanoparticle stabilizer. The variability of ...

EPFL2016

Synthesis of Azoimidazolium Dyes with Nitrous Oxide

Rosario Scopelliti, Kay Severin, Euro Solari, Alexander Tskhovrebov

A new method for the synthesis of industrially important azoimidazolium dyes is presented. The procedure is based on a reagent which is rarely used in the context of synthetic organic chemistry: nitrous oxide (“laughing gas”). N2O is first coupled to N-het ...

Wiley-Blackwell2015

Palladium-Catalyzed Through-Space C(sp3)-H and C(sp2)-H Bond Activation by 1,4-Palladium Migration: Efficient Synthesis of [3,4]- Fused Oxindoles

Jieping Zhu, Qian Wang, Ala Bunescu

Palladium two step: Linear anilides were converted into the title compounds in good to excellent yields through a palladium-catalyzed domino carbopalladation/1,4-palladium shift sequence. The C(sp3)-H activation involves a seven-membered palladacycle, and ...

Wiley-Blackwell2013