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Related publications (29)

Fragmentation mechanism of UV-excited peptides in the gas phase

Thomas Rizzo, Oleg Boyarkine, Michael Zachary Kamrath, Aleksandra Zabuga

We present evidence that following near-UV excitation, protonated tyrosine- or phenylalanine–containing peptides undergo intersystem crossing to produce a triplet species. This pathway competes with direct dissociation from the excited electronic state and ...

American Institute of Physics2014

Electronic elements based on quasitwo-dimensional electron/hole gas at charged domain walls in ferroelectrics

Alexander Tagantsev, Tomas Sluka

The present invention relates to a device including a ferroic material having a ferroelectric order parameter and including at least two domains, as well as a first and second electrode in electrical contact with the ferroic material. The device is configu ...

2014

Assigning the EPR Fine Structure Parameters of the Mn(II) Centers in Bacillus subtilis Oxalate Decarboxylase by Site-Directed Mutagenesis and DFT/MM Calculations

Ursula Röthlisberger, Pablo Campomanes Ramos

Oxalate decarboxylase (OxDC) catalyzes the Mn-dependent conversion of the oxalate monoanion into CO2 and formate. EPR-based strategies for investigating the catalytic mechanism of decarboxylation are complicated by the difficulty of assigning the signals a ...

2014

Magnetism and Atomic Scale Structure of Bimetallic Nanostructures at Surfaces

Sergio Vlaic

his thesis reports on the magnetic properties of bi- and tri-metallic nanostructures at surfaces. The main goal is to build the smallest nanostructure ferromagnetic at room temperature and the assembly of those structures in high density arrays. To this pu ...

EPFL2013

Structural phase transitions and electronic phenomena at 180-degree domain walls in rhombohedral BaTiO3

Alexander Tagantsev, Nava Setter, Petr Yudin

The structure and electronic phenomena at the 180-degree domain wall in the rhombohedral phase of BaTiO3 are described using Landau-Ginzburg-Devonshire theory. Dependent on the wall orientation, two types of domain wall behaviors are identified. The low-en ...

American Physical Society2013

Highly cytotoxic trithiophenolatodiruthenium complexes of the type [(eta(6)-p-MeC6H4Pr (i) )(2)Ru-2(SC6H4-p-X)(3)](+): synthesis, molecular structure, electrochemistry, cytotoxicity, and glutathione oxidation potential

Paul Joseph Dyson, Olivier Pierre Zava, Mathurin Baquié

A series of cationic dinuclear p-cymene ruthenium trithiophenolato complexes of the type (eta(6)-p-MeC6H4Pr (i) )(2)Ru-2(SC6H4-p-X)(3) (1 X is H, 2 X is Me, 3 X is Ph, 4 X is Br, 5 X is OH, 6 X is NO2, 7 X is OMe, 8 X is CF3, 9 X is F, 10 X is Pr (i) ...

Springer2012

Ultrafast (but Many-Body) Relaxation in a Low-Density Electron Glass

We present a study of the relaxation dynamics of the photoexcited conductivity of the impurity states in the low-density electronic glass, phosphorous-doped silicon Si: P. Using subband gap optical pump-terahertz probe spectroscopy we find strongly tempera ...

American Physical Society2010

Charge ordering in substituted and non-stoichiometric BaVS3

Helmuth Berger, László Forró, Ana Akrap

Among the correlated electronic systems, BaVS3 which exhibits both itinerant and localized states as well as a subtle interplay betwen charge, orbital, spin and lattice degrees of freedom, is a model system. Its electronic structure consists in a broad qua ...

2010

Magnetism of individual adatoms and of epitaxial monolayers

Anne Lehnert

This thesis reports on the magnetism of low coordinated Fe and Co atoms in different chemical and electronic environments. The objective of this research was to contribute to the fundamental understanding of the magnetic properties, such as magneto-crystal ...

EPFL2009