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Related publications (29)

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Amphiphilic Iodine(III) Reagents for the Lipophilization of Peptides in Water

Jérôme Waser, Durga Prasada Rao Hari, Romain Gaëtan Tessier, Abhaya Kumar Mishra

We report the functionalization of cysteine residues with lipophilic alkynes bearing a silyl group or an alkyl chain using amphiphilic ethynylbenziodoxolone reagents (EBXs). The reactions were carried out in buffer (pH 6 to 9), without organic co-solvent o ...

Wiley-VCH Verlag GmbH2021

A mixture model for a dilute dispersion of gas in a liquid flow: Mathematical analysis and application to aluminium electrolysis

Jacques Rappaz, Marco Picasso, Emile Tryphon Pierre Soutter

A mixture model to take into account the flow of small carbon dioxide bubbles dissolved in a liquid is presented. The model describes the evolution of the velocity fields (mixture and gas), the pressure and the volume fraction of gas. The system of equatio ...

2021

Methods for the generation of large combinatorial macrocycle libraries

Sevan Mleh Habeshian

Macrocycles are an attractive class of molecules due to their good binding properties and yet rather small size that allows, in many cases, crossing membranes to reach intracellular targets. In comparison to classical small molecule drugs, macrocycles are ...

EPFL2021

Super adsorption performance of carboxymethyl cellulose/copper oxide-nickel oxide nanocomposite toward the removal of organic and inorganic pollutants

Shaik Mohammed Zakeeruddin

A novel nanocomposite bead based on polymeric matrix of carboxymethyl cellulose and copper oxide-nickel oxide nanoparticles was synthesized, characterized, and applied for adsorptive removal of inorganic and organic contaminants at trace level of part per ...

SPRINGER HEIDELBERG2021

Diformylxylose as a new polar aprotic solvent produced from renewable biomass

Jeremy Luterbacher, Anastasiia Komarova, Graham Reid Dick

Lignin is a promising candidate for the replacement of fossil-based materials, due to its natural abundance and aromatic structure. This same structure poses major challenges to lignin's exploitation for material development. The harsh conditions generally ...

2021

The Solvent Effect on H2O2 Generation at Room Temperature Ionic Liquid|Water Interface

Hubert Girault

H2O2 is a versatile chemical and can be generated by the oxygen reduction reaction (ORR) in proton donor solution in molecular solvents or room temperature ionic liquids (IL). We investigated this reaction at interfaces formed by eleven hydrophobic ILs and ...

2021

A polymeric ionic liquid catalyst for the N-formylation and N-methylation of amines using CO2/PhSiH3

Paul Joseph Dyson, Andreas Züttel, Zhaofu Fei, Kyriakos Stylianou, Arunraj Chidambaram, Aswin Gopakumar, Dmitry Vasilyev, Serhii Shyshkanov

We describe a polymeric ionic liquid (PIL) derived from trimethyl(p-vinylbenzyl)ammonium chloride ([VBTAm]Cl) that efficiently catalyzes the N-formylation of amines employing CO2 and PhSiH3 at room temperature with low catalyst loadings in near-quantitativ ...

2020

Shape Engineering of Metal-Organic Frameworks via MOF@Polymer Composite Fabrication

Bardiya Valizadeh

Metal-organic frameworks (MOFs) are a fascinating class of porous materials that have become the subject of research owing to their unique characteristics such as high surface areas, low densities, and structural tunability. Recently, the research has been ...

EPFL2020

Preparation of Highly Porous Metal-Organic Framework Beads for Metal Extraction from Liquid Streams

Emad Oveisi, Wendy Lee Queen, Shuliang Yang, Daniel Teav Sun, Li Peng, Olga Trukhina, Ilia Kochetygov, Olga Syzgantseva, Anita Justin

Metal-organic frameworks (MOFs) offer great promise in a variety of gas- and liquid-phase separations. However, the excellent performance on the lab scale hardly translates into pilot- or industrial-scale applications due to the microcrystalline nature of ...

AMER CHEMICAL SOC2020