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Concept

Volume (thermodynamics)

Related publications (25)

An in-situ 3D micro-XRD investigation of water uptake by alkali-silica-reaction (ASR) product

Solène Anne-Lise Albinski

The ASR products in concrete have various chemical compositions. It is yet unclear whether and how these products develop micro-expansion upon moisture ingress. This paper presents a 3D in-situ observation of the crystallography and volume change of an ASR ...

Pergamon-Elsevier Science Ltd2021

Volume change characteristics of fine-grained soils due to sequential thermo-mechanical stresses

Alessio Ferrari

Know-how of volume change characteristics, VCC, of the fine-grained soils, exposed to thermal stresses, is essential for design of various thermo-active structures. These stresses are known to induce excess pore-water pressure, Δu θ , in the saturated stat ...

2019

Micropipette calibration by differential pressure measurements

Philippe Renaud, David Vincent Bonzon

The pipetting of small volumes, typically ranging between a few and one thousand microliters (mu l), is widely used in many laboratories and essentially relies on air displacement to aspirate and dispense the liquid contained in a small plastic tip. ...

IOP Publishing2019

Biomembrane modeling with isogeometric analysis

Alfio Quarteroni, Luca Dede', Andrea Bartezzaghi

We consider the numerical approximation of lipid biomembranes at equilibrium described by the Canham-Helfrich model, according to which the bending energy is minimized under area and volume constraints. Energy minimization is performed via L-2-gradient flo ...

ELSEVIER SCIENCE SA2019

Thermodynamic properties of the Shastry-Sutherland model throughout the dimer-product phase

Frédéric Mila, Bruce Normand

The thermodynamic properties of the Shastry-Sutherland model have posed one of the longest-lasting conundrums in frustrated quantum magnetism. Over a wide range on both sides of the quantum phase transition (QPT) from the dimer-product state to the plaquet ...

2019

Three-dimensional phase-field study of grain coarsening and grain shape accommodation in the final stage of liquid-phase sintering

Liesbeth Maria L Vanherpe

A 3-dimensional phase-field model is implemented to simulate the grain evolution in the final stage of liquid-phase sintering. The model considers a liquid phase and a polycrystalline solid phase. Results for varying ratios of the solid-solid interface ene ...

Elsevier Sci Ltd2017

Partial Molar Volumes of Aqua Ions from First Principles

Alfredo Pasquarello, Julia Anna Wiktor

Partial molar volumes of ions in water solution are calculated through pressures obtained from ab initio molecular dynamics simulations. The correct definition of pressure in charged systems subject to periodic boundary conditions requires access to the va ...

Amer Chemical Soc2017

Water retention behaviour of compacted bentonites: experimental observations and constitutive model

Anne-Catherine Adolphine M Dieudonné

Bentonite-based materials are studied as potential barriers for the geological disposal of radioactive waste. In this context, the hydro-mechanical behaviour of the engineered barrier is first characterized by free swelling conditions followed by constant ...

EDP Sciences2016

Water at Interfaces

Gabriele Tocci, Martin Hangaard Hansen

The interfaces of neat water and aqueous solutions play a prominent role in many technological processes and in the environment. Examples of aqueous interfaces are ultrathin water films that cover most hydrophilic surfaces under ambient relative humidities ...

American Chemical Society2016

Predicting the yield stress of paraffin-wax suspensions

Paul Bowen

An empirical modification of the Yodel model was developed for the prediction of the yield stress of concentrated, particulate, paraffin-wax suspensions, with a solids loading in the range of 47-57 vol.%, used in the low-pressure injection moulding (LPIM). ...

Elsevier2016

Thermodynamic properties of highly frustrated quantum spin ladders: Influence of many-particle bound states

Frédéric Mila, Bruce Normand

Quantum antiferromagnets have proven to be some of the cleanest realizations available for theoretical, numerical, and experimental studies of quantum fluctuation effects. At finite temperatures, however, the additional effects of thermal fluctuations in t ...

2016

Measurement of Mechanical Coherency Temperature and Solid Volume Fraction in Al-Zn Alloys Using In Situ X-ray Diffraction During Casting

Jean-Marie Drezet, Güven Kurtuldu, Bastien Gilbert Pierre Mireux

During solidification of metallic alloys, coalescence leads to the formation of solid bridges between grains or grain clusters when both solid and liquid phases are percolated. As such, it represents a key transition with respect to the mechanical behavior ...

Springer Verlag2015

Early precipitation during cooling of an Al-Zn-Mg-Cu alloy revealed by in situ small angle X-ray scattering

Jean-Marie Drezet, Helena Van Swygenhoven, Patrick Schloth

Early subnanometre cluster formation during quenching of a high-strength AA7449 aluminium alloy was investigated using in situ small angle X-ray scattering. Fast quench cooling was obtained by using a laser-based heating system. The size and number density ...

American Institute of Physics2014

Solid Solutions of Lead Metaniobate-Stabilization of the Ferroelectric Polymorph and the Effect on the Lattice Parameters, Dielectric, Ferroelectric, and Piezoelectric Properties

Nava Setter, Dragan Damjanovic, Alberto Biancoli, Barbara Maraston Fraygola

Ferroelectric orthorhombic lead metaniobate (PbNb2O6) is known to be metastable with respect to the thermodynamically stable nonferroelectric rhombohedral polymorph. The high-temperature tetragonal to low temperature rhombohedral phase transition is recons ...

Wiley-Blackwell2014

On the water retention behaviour of shales

Lyesse Laloui, Alessio Ferrari, Valentina Favero

Shales are among the most considered geomaterials in current energy-related geomechanical investigations; they are involved in engineering applications such as the unconventional extraction of natural gas, CO2 sequestration and nuclear waste geological sto ...

2014

Free volume in ionic liquids: a connection of experimentally accessible observables from PALS and PVT experiments with the molecular structure from XRD data

Safak Bulut

In the current work, free volume concepts, primarily applied to glass formers in the literature, were transferred to ionic liquids (ILs). A series of 1-butyl-3-methylimidazolium (C4MIM) based ILs was investigated by Positron Annihilation Lifetime Spec ...

Royal Soc Chemistry2013

On the relevance of volume increase for the length changes of mortar bars in sulfate solutions

Karen Scrivener

The ingress of sulfate ions into cementitious materials leads to the formation of ettringite, gypsum and other phases. The increase in solid volume through the formation of these phases is often assumed to be the only reason for expansion. In this paper we ...

Pergamon-Elsevier Science Ltd2013

Advances in the Testing of the Hydro-mechanical Behaviour of Shales

Lyesse Laloui, Alessio Ferrari

The paper presents some of the advanced experimental techniques and apparatuses that have been developed by the authors for testing the hydro-mechanical behaviour of shales. A methodology established for the analysis of the water retention behaviour in non ...

Springer2012

Effective hydrogen diffusion coefficient for solidifying aluminium alloys

Michel Rappaz, Ludger Weber

An effective hydrogen diffusion coefficient has been calculated for two solidifying Al - 4.5 wt.% Cu and Al - 10 wt.% Cu alloys as a function of the volume fraction of solid. For this purpose, in situ X-ray tomography was performed on these alloys. For eac ...

Elsevier2011

Thermodynamic Calculations for Biochemical Transport and Reaction Processes in Metabolic Networks

Vassily Hatzimanikatis

Thermodynamic analysis of metabolic networks has recently generated increasing interest for its ability to add constraints on metabolic network operation, and to combine metabolic fluxes and metabolite measurements in a mechanistic manner. Concepts for the ...

Elsevier2010