Saturated and unsaturated compounds

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Characterization of hepatic fatty acids in mice with reduced liver fat by ultra-short echo time (1) H-MRS at 14.1 T in vivo

Rolf Gruetter, Ana Francisca Leal Silva Soares, Hongxia Lei

Alterations in the hepatic lipid content (HLC) and fatty acid composition are associated with disruptions in whole body metabolism, both in humans and in rodent models, and can be non-invasively assessed by (1) H-MRS in vivo. We used (1) H-MRS to character ...

Wiley-Blackwell2015

Structural Modification of Ni/gamma-Al2O3 with Boron for Enhanced Carbon Resistance during CO Methanation

Davide Ferri

Carbon deposition during CO methanation from biomass-derived gas is a significant challenge in terms of catalyst lifetime. It results from the severe reaction conditions imposed by the presence of unsaturated hydrocarbons in the gasified feedstock. This wo ...

Wiley-VCH Verlag2015

Development of prediction models for the reactivity of organic compounds with ozone in aqueous solution by quantum chemical calculations: Role of delocalized and localized molecular orbitals

Urs von Gunten, Jeremy Samuel Arey, Minju Lee, Saskia Gisela Zimmermann-Steffens

Second-order rate constants (k(O3)) for the reaction of ozone with micropollutants are essential parameters for the assessment of micropollutant elimination efficiency during ozonation in water and wastewater treatment. Prediction models for k(O3) were dev ...

Amer Chemical Soc2015

Resolving biodegradation patterns of persistent saturated hydrocarbons in weathered oil samples from the Deepwater Horizon disaster

Jeremy Samuel Arey, Jonas Gros

Biodegradation plays a major role in the natural attenuation of oil spills. However, limited information is available about biodegradation of different saturated hydrocarbon classes in surface environments, despite that oils are composed mostly of saturate ...

Amer Chemical Soc2014

Solute transport in nearly saturated porous media under landfill clay liners: A finite deformation approach

David Andrew Barry

For solute transport in a deformable clay liner, the importance of consolidation in the presence of sorption and consolidation-induced advection are well known. Here a one-dimensional coupled consolidation and solute transport model for a partially saturat ...

Elsevier Science Bv2013

Naphthalimide-tagged ruthenium-arene anticancer complexes: combining coordination with intercalation

Paul Joseph Dyson, Catherine Marie Amélie Clavel, Fabio Edafe, Kelly Joan Kilpin

Ruthenium(II) arene compounds have been modified with the naphthalimide group, tethered via the arene ligand, i.e. {dichloroeta(6)-N-(phenylalkyl)(4-dimethylamino)-1,8-naphthalimideruthenium(II)} (alkyl = methyl, ethyl, propyl, pta = 1,3,5-triaza-7- ...

American Chemical Society2012

Challenges and Opportunities in the Development of Organometallic Anticancer Drugs

Paul Joseph Dyson, Christian Hartinger

This review provides an introduction into the fascinating area of organometallic anticancer compounds. Although the subject dates back many years, it has witnessed considerable growth only in the past decade. A brief overview of the subject together with r ...

Amer Chemical Soc2012

Influence of arene dissociation and phosphine coordination on the catalytic activity of [RuCl(kappa(2)-triphos)(p-cymene)]PF6

Paul Joseph Dyson

The catalytic activity of a ruthenium(II)-p-cymene complex containing a partially coordinated triphosphine ligand, [RuCl(kappa(2)-triphos)(p-cymene)]PF6 1, has been investigated in the hydrogenation of styrene to ethylbenzene. The influence of arene dissoc ...

2011

The biphenyl-monitored effective size of unsaturated functional or fluorinated ortho substituents

The size of a series of typical substituents has been probed by dynamic NMR measurements of the barriers to aryl-aryl rotation of the corresponding biphenyls. The resulting B values are meaningful because only mono-ortho substituted compounds were investig ...

2010

Multi-physical processes in geomechanics. An introduction to constitutive modeling and coupling aspects

Lyesse Laloui

This paper is the basis for a course dedicated to the geomechanics modelling, taking into account multiphysics couplings. A number of different coupling are discussed, with respectively the fluid flow (saturated and unsaturated) and the thermal transfers i ...

2009