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Concept

Isocyanide

Related publications (28)

Iron Complexes for Hydrogen Activation and Catalytic Hydrogenation

Simona Mazza

Inspired by Nature several groups have developed structural and functional iron complexes mimicking the active site of the iron-hydrogenases, which show high reactivity in the H2 cleavage. Usually pendant bases have been incorporated onto families of Fe co ...

EPFL2015

Synthesis and Reactivity of Mononuclear Iron Models of [Fe]-Hydrogenase that Contain an Acylmethylpyridinol Ligand

Xile Hu, Dafa Chen

[Fe]-hydrogenase has a single iron-containing active site that features an acylmethylpyridinol ligand. This unique ligand environment had yet to be reproduced in synthetic models; however the synthesis and reactivity of a new class of small molecule mimics ...

Wiley-V C H Verlag Gmbh2014

Cyclization and annulation reactions of nitrogen-substituted cyclopropanes and cyclobutanes

Jérôme Waser, Fides Benfatti, Florian Patrick Marie Daniel De la Barre De Nanteuil, Reto Frei, Filippo De Simone, Eloísa Sofía Serrano Robledo

Cyclization and annulation reactions initiated by ring-opening of small rings, especially cyclopropanes and cyclobutanes are now well-established in synthetic chemistry. Nevertheless, the potential of aminocyclopropanes and cyclobutanes, an important subcl ...

Royal Society of Chemistry2014

Extreme Tuning of Redox and Optical Properties of Cationic Cyclometalated Iridium(III) Isocyanide Complexes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti

We report seven heteroleptic cationic iridium(III) complexes with cyclometalating N-arylazoles and alkyl/aryl isocyanides, ((CN)-N-boolean AND)(2)Ir(CNR)(2), and characterize two of them by crystal structure analysis. The complexes are air- and m ...

American Chemical Society2013

Bright Blue Phosphorescence from Cationic Bis-Cyclometalated Iridium(III) Isocyanide Complexes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti

We report new bis-cyclometalated cationic indium(III) complexes ((CN)-N-boolean AND)(2)Ir(CN-tert-Bu)(2) that have tert-butyl isocyanides as neutral auxiliary ligands and 2-phenylpyridine or 2-(4'-fluoropheny1)-R-pyridines (where R is 4-methoxy, ...

2012

Blue Phosphorescence of Trifluoromethyl- and Trifluoromethoxy-Substituted Cationic Iridium(III) Isocyanide Complexes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti

We report the first comprehensive comparative synthetic, structural, electrochemical, and spectroscopic study of an extended series of fluorocarbon-modified iridium(III) complexes. We prepared seven new cationic Ir(III) complexes with tert-butyl isocyanide ...

American Chemical Society2012

Enol Phosphinates and Phosphonates: Practical Electrophiles for Cross-Coupling Strategies

Enol phosphinates and phosphonates can be readily prepared from simple lactams in high yields and are both stable and storable. Both these substrates can be employed successfully in homogeneous Suzuki-Miyaura and Stille cross-couplings protocols. Additiona ...

Georg Thieme Verlag2009

Regioselectivity in aqueous palladium catalysed hydroxycarbonylation of styrene: a catalytic and mechanistic study

Gabor Laurenczy, Anisoara Ionescu

Regioselectivity control was studied in palladium catalyzed hydroxycarbonylation of styrene in neat water with water-sol. phosphines, mostly trisulfonated triphenylphosphine, TPPTS, but also N-bis(N',N'-diethyl-2-aminoethyl)-4-aminomethylphenyl-diphenylpho ...

2006