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Concept

Inhalant

Related publications (6)

A multi-scale time-resolved study of photoactivated dynamics in 5-benzyl uracil, a model for DNA/protein interactions

Majed Chergui, Enrico Pomarico

We combine fluorescence up-conversion and time correlated single photon counting experiments to investigate the 5-benzyl uracil excited state dynamics in methanol from 100 fs up to several ns. This molecule has been proposed as a model for DNA/protein inte ...

2019

Fixation of nitrous oxide by mesoionic and carbanionic N-heterocyclic carbenes

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Euro Solari, Léonard Yannick Maurice Eymann, Giacomo Cecot

A ditopic carbanionic N-heterocyclic carbene was found to react with the inert gas nitrous oxide, resulting in a stable covalent adduct with two intact N2O groups attached to the heterocycle. Mesoionic N-heterocyclic carbenes derived from C2-arylated 1,3-b ...

Royal Society of Chemistry2017

Solvent effects in catalysis: rational improvements of catalysts via manipulation of solvent interactions

Paul Joseph Dyson

In homogeneous catalysis, the main emphasis on improving catalyst performance (rate, yield and selectivity) is directed towards manipulation of the ligands. The steric and electronic effects of ligands are extremely well understood and the rational design ...

2016

One-pot gold-catalyzed synthesis of 3-silylethynyl indoles from unprotected o-alkynylanilines

Jérôme Waser, Jonathan Brand

The Au(III)-catalyzed cyclization of 2-alkynylanilines was combined in a one-pot procedure with the Au(I)-catalyzed C3-selective direct alkynylation of indoles using the benziodoxolone reagent TIPS-EBX to give a mild, easy and straightforward entry to 2-su ...

2011

Detection of Farnesyltransferase Interface Hot Spots through Computational Alanine Scanning Mutagenesis

In this study, we present a detailed characterization of the full α/β interface in the farnesyltransferase (FTase) enzyme, an important target in drug design efforts. This characterization is presented in terms of hot spots, warm spots, and null spots and ...

2011

Solvent Effect on Redox Properties of Hexanethiolate Monolayer-Protected Gold Nanoclusters

Hubert Girault, Bin Su

The capacitance of monolayer-protected gold nanoclusters (MPCs), CMPC, in solution has been theoretically reconsidered from an electrostatic viewpoint, in which an MPC is considered as an isolated charged sphere within two dielectric layers, the intrinsic ...

2006