Molar heat capacity

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Thermal Engineering of Metal-Organic Frameworks for Adsorption Applications: A Molecular Simulation Perspective

Venkat Kapil

Thermal engineering of metal-organic frameworks for adsorption-based applications is very topical in view of their industrial potential, in particular, since heat management and thermal stability have been identified as important obstacles. Hence, a fundam ...

AMER CHEMICAL SOC2019

The Deformation Capacity of Lap Splices in RC Walls: From Experimental Testing to Numerical Modelling

Danilo Tarquini

Field observations as well as experimental tests have shown that both the strength and displacement capacity of reinforced concrete (RC) members might be significantly reduced by the presence of lap splices. This degradation applies in particular if the lo ...

EPFL2019

Effect of Thermal Cycling on the Structural Evolution of Methylammonium Lead Iodide Monitored around the Phase Transition Temperatures

László Forró, Endre Horvath, Alla Arakcheeva, Gaétan Charles Antoine Giriat, Anastasiia Glushkova, Konstantins Mantulnikovs, Konstantin Semeniuk

Optoelectronic devices and solar cells based on organometallic hybrid perovskites have to operate over a broad temperature range, which may contain their structural phase transitions. For instance, the temperature of 330 K, associated with the tetragonal-c ...

2019

Mechanical Model for Drift-Induced Punching of Slab-Column Connections without Transverse Reinforcement

Aurelio Muttoni, Katrin Beyer, Ioannis Sokratis Drakatos

A mechanical model is presented for predicting the momentrotation relationship of interior slab-column connections without transverse reinforcement when subjected to seismically induced drifts. The model accounts explicitly for the three load-transfer acti ...

2018

Re-assessing the Formation of N-nitrosamines during Chloramination of Various Nitrogenous Compounds using Specific and Total N-nitrosamines Analysis

Urs von Gunten, Florian Frédéric Vincent Breider

N-nitrosamines (NOAs) are potent carcinogenic and mutagenic compounds that can be present in water, biological fluids, food, consumer products and cigarette smoke. Several studies have shown that the formation of NOAs in water can arise from the reactions ...

2018

alpha-Diimine homologues of cisplatin: synthesis, speciation in DMSO/water and cytotoxicity

Paul Joseph Dyson, Lucinda Kate Batchelor

The Pt(ii) -diimine complexes [PtCl2{N-2-(HCNR)(2)}] (R = C6H11, 1; 4-C6H10OH, 2; 4-C6H4CH3, 3; 4-C6H4OH, 4) and [PtCl2{N-2-(CH3CNOH)(2)}] (5) were prepared in 60-81% yields from the 1:1 molar reactions of cis-[PtCl2(DMSO)(2)] with the appropriate -diimine ...

ROYAL SOC CHEMISTRY2018

The underappreciated role of nonvolatile cations in aerosol ammonium-sulfate molar ratios

Athanasios Nenes, Hairun Guo

Overprediction of fine-particle ammonium-sulfate molar ratios (R) by thermodynamic models is suggested as evidence for interactions with organic constituents that inhibit the equilibration of gas-phase ammonia with aerosol sulfate and questions the equilib ...

Copernicus Publications2018

J1−J2 square-lattice Heisenberg antiferromagnets with 4d1 spins: AMoOPO4Cl (A=K,Rb)

Henrik Moodysson Rønnow, Peter Babkevich

Magnetic properties of AMoOPO4Cl (A=K,Rb) with Mo5+ ions in the 4d1 electronic configuration are investigated by magnetization, heat capacity, and nuclear magnetic resonance (NMR) measurements on single crystals, combined with powder neutron diffraction ex ...

2017

Influence of Lap Splices on the Deformation Capacity of RC Walls. I: Database Assembly, Recent Experimental Data, and Findings for Model Development

Katrin Beyer, João Saraiva Esteves Pacheco de Almeida, Danilo Tarquini

Recent postearthquake missions have shown that reinforced concrete (RC) wall buildings can experience critical damage owing to lap splices, which led to a recent surge in experimental tests of walls with such constructional details. Most of the 16 wall tes ...

Asce-Amer Soc Civil Engineers2017

J1-J2 square lattice antiferromagnetism in the orbitally quenched insulator MoOPO4

László Forró, Henrik Moodysson Rønnow, Helmuth Berger, Arnaud Magrez, Oleg Yazyev, Bálint Náfrádi, Ivica Zivkovic, Peter Babkevich, Lin Yang, Noore Elahi Shaik

We report magnetic and thermodynamic properties of a 4d1 (Mo5+) magnetic insulator MoOPO4 single crystal, which realizes a J1−J2 Heisenberg spin-1/2 model on a stacked square lattice. The specific-heat measurements show a magnetic transition at 16 K which ...

Amer Physical Soc2017