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Concept

Exergy

Related publications (20)

Decarbonizing the fertilizers sector: an alternative pathway for urea and nitric acid production

François Maréchal, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos

In order to alleviate the environmental impact that nitrogen fertilizers production is responsible for, several efforts have been addressed to incentivize the partial or total decarbonization of the supply chains of ammonia and its derivatives. The decarbo ...

2024

Plasmonic Nanostructures for Photocatalysis: Material, Photonic and Electronic Effects

Fateme Kiani Shahvandi

Plasmonic photochemistry has a large potential to replace energy-intensive chemical processes with low-temperature, low-pressure light-driven chemical reactions. Plasmonic nanostructures have emerged as promising photocatalysts with exceptional and tunable ...

EPFL2024

Thermodynamic bounds on time-reversal asymmetry

Shiling Liang

Quantifying irreversibility of a system using finite information constitutes a major challenge in stochastic thermodynamics. We introduce an observable that measures the time-reversal asymmetry between two states after a given time lag. Our central result ...

Amer Physical Soc2023

Process modeling and integration of hydrogen and synthetic natural gas production in a kraft pulp mill via black liquor gasification

François Maréchal, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos

The black liquor gasification integrated to chemical plants has shown potential for reducing the process irreversibility and promoting the decarbonization of this industrial sector. In the integrated chemical plants proposed in this work, the purpose is co ...

Pergamon-Elsevier Science Ltd2023

Information Spectrum Converse for Minimum Entropy Couplings and Functional Representations

Yanina Yurina Shkel, Anuj Kumar Yadav

Given two jointly distributed random variables (X,Y), a functional representation of X is a random variable Z independent of Y, and a deterministic function g(⋅,⋅) such that X=g(Y,Z). The problem of finding a minimum entropy functional representation is kn ...

2023

Techno-economic and environmental analysis of methanol and dimethyl ether production from syngas in a kraft pulp process

François Maréchal, Daniel Alexander Florez Orrego

The conventional configuration of a pulp mill, in which black liquor is concentrated and burnt, is compared to the upgrading gasification routes for methanol (MeOH) or dimethyl ether (DME) co-production. To this end, various exergy-based and environmental ...

PERGAMON-ELSEVIER SCIENCE LTD2022

Atmospheric biogenic volatile organic compounds in the Alaskan Arctic tundra: constraints from measurements at Toolik Field Station

Hélène Paule Angot

The Arctic is a climatically sensitive region that has experienced warming at almost 3 times the global average rate in recent decades, leading to an increase in Arctic greenness and a greater abundance of plants that emit biogenic volatile organic compoun ...

Copernicus GmbH2022

Two novel cogeneration charging stations for electric vehicles: Energy, exergy, economic, environment, and dynamic characterizations

Jan Van Herle, Hossein Pourrahmani

This paper suggests two novel designs for the electric vehicle charging stations using LiMn2O4 Lithium-ion battery and based on a Solid Oxide Fuel Cell (SOFC) and absorption refrigeration cycle (ARC) technologies to provide electricity and cooling, respect ...

Elsevier2022

Symbolic kinetic models in python (SKiMpy): intuitive modeling of large-scale biological kinetic models

Vassily Hatzimanikatis, Maria Masid Barcon, Georgios Fengos, Daniel Robert Weilandt, Pierre Guy Rémy Salvy, Zhaleh Hosseini

Motivation: Large-scale kinetic models are an invaluable tool to understand the dynamic and adaptive responses of biological systems. The development and application of these models have been limited by the availability of computational tools to build and ...

Oxford University Press2022

Exergy and exergoeconomic analyses of sustainable furfural production via reactive distillation

François Maréchal

Lignocellulosic biomass is a potential renewable resource for production of high-value, sustainable products. Furfural is among the important bio-based chemicals in biorefineries. However, the conventional process of furfural production using a reaction-se ...

2021

On the Application of Small-Scale Turbines in Industrial Steam Networks

François Maréchal, Jürg Alexander Schiffmann, Ivan Daniel Kantor, Ansgar Weickgenannt

This study investigates the technical and economic feasibility of replacing throttling valves with smale-scale, oil-free turbomachinery in industrial steam networks. This is done from the perspective of the turbomachine, which has to be integrated into a n ...

2021

Finite-temperature materials modeling from the quantum nuclei to the hot electron regime

Michele Ceriotti, Chiheb Ben Mahmoud, Nataliya Lopanitsyna

Atomistic simulations provide insights into structure-property relations on an atomic size and length scale, that are complementary to the macroscopic observables that can be obtained from experiments. Quantitative predictions, however, are usually hindere ...

2021

Surface energy contributions to the work of infiltration in metal matrix composite processing

Andreas Mortensen, Gionata Schneider

The work needed to mechanically drive molten metal into a porous solid preform when producing a composite material by infiltration can significantly exceed the energy change required for thermodynamically reversible infiltration. We measure, by quantitativ ...

2021

Spatio-temporal modeling of the crowding conditions and metabolic variability in microbial communities

Vassily Hatzimanikatis, Liliana Angeles Martinez

The metabolic capabilities of the species and the local environment shape the microbial interactions in a community either through the exchange of metabolic products or the competition for the resources. Cells are often arranged in close proximity to each ...

2021

Combined exergy analysis, energy integration and optimization of syngas and ammonia production plants: A cogeneration and syngas purification perspective

François Maréchal, Daniel Alexander Florez Orrego, Shivom Sharma

Modern ammonia production plants are equipped with efficient energy integration networks able to recover an important fraction of the waste heat exergy available throughout the chemical system. However, in order to drive the endothermic reforming reactions ...

ELSEVIER SCI LTD2020

Exergy assessment and techno-economic optimization of bioethanol production routes

François Maréchal

Currently, electricity generation and second-generation ethanol production from lignocellulosic feedstocks represent technological alternatives in the bioenergy sector. Nevertheless, the introduction of new production processes denotes a real challenge due ...

2020

Multi-objective optimization and exergoeconomic analysis of a continuous solar-driven system with PCM for power, cooling and freshwater production

Hossein Pourrahmani

In this article, three different modes of a novel integrated system would be evaluated by the application of high temperature Thermal Energy Storage (TES) to produce electricity, cooling, and freshwater. Freshwater is produced using the reverse osmosis (RO ...

Elsevier2020

Large-scale kinetic metabolic models of Pseudomonas putida KT2440 for consistent design of metabolic engineering strategies

Vassily Hatzimanikatis, Ljubisa Miskovic, Milenko Tokic

Background: Pseudomonas putida is a promising candidate for the industrial production of biofuels and biochemicals because of its high tolerance to toxic compounds and its ability to grow on a wide variety of substrates. Engineering this organism for impro ...

2020

Analysis of the sorption-enhanced chemical looping biomass gasification process: Performance assessment and optimization through design of experiment approach

François Maréchal, Thanaphorn Detchusananard

In this study, the performance of high-purity hydrogen production through the sorption-enhanced chemical looping gasification (SECLG) process, involving a gasifier, calciner, and air reactor, was investigated. In this process, the biomass feedstock was woo ...

2020

Investigation of femtosecond laser-tuned thermomechanical properties of fused silica

Pieter Vlugter

The thermomechanical properties of materials are among the most important properties for designing precision instruments, in particular for devices seeking high-dimensional stability, invariant temperature-elastic properties or low thermoelastic losses. De ...

EPFL2020